Literature DB >> 20201572

Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes.

Zoë R Turner1, Ronan Bellabarba, Robert P Tooze, Polly L Arnold.   

Abstract

Silyl, phosphinyl, stannyl, and boryl reagents can be added across the neutral metal-carbon dative bond in d(0) f-block metal N-heterocyclic carbene complexes in a reversible manner, allowing additional functional groups to be incorporated into redox-inactive organo-f-block compounds.

Entities:  

Year:  2010        PMID： 20201572     DOI： 10.1021/ja910673q

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Unexpected C(carbene)-X (X: I, Br, Cl) Reductive Elimination From N-Heterocyclic Carbene Copper Halide Complexes Under Oxidative Conditions.

Authors:  Bo-Lin Lin; Peng Kang; T Daniel P Stack
Journal:  Organometallics       Date:  2010-09-13       Impact factor: 3.876

Review 2.  Recent Advances in Catalysis Involving Bidentate N-Heterocyclic Carbene Ligands.

Authors:  Abdollah Neshat; Piero Mastrorilli; Ali Mousavizadeh Mobarakeh
Journal:  Molecules       Date:  2021-12-24       Impact factor: 4.411

3.  Divergent uranium- versus phosphorus-based reduction of Me3SiN3 with steric modification of phosphido ligands.

Authors:  Robert J Ward; Pokpong Rungthanaphatsophon; Iker Del Rosal; Steven P Kelley; Laurent Maron; Justin R Walensky
Journal:  Chem Sci       Date:  2020-05-27       Impact factor: 9.825

4.  Synergic Deprotonation Generates Alkali-Metal Salts of Tethered Fluorenide-NHC Ligands Co-Complexed to Alkali-Metal Amides.

Authors:  Kieren J Evans; Stephen M Mansell
Journal:  Chemistry       Date:  2019-02-19       Impact factor: 5.236
  4 in total

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