| Literature DB >> 20199070 |
Yong Yan1, Irvin Telepeni, Sihai Yang, Xiang Lin, Winfried Kockelmann, Anne Dailly, Alexander J Blake, William Lewis, Gavin S Walker, David R Allan, Sarah A Barnett, Neil R Champness, Martin Schröder.
Abstract
Neutron powder diffraction experiments on D(2)-loaded NOTT-112 reveal that the axial sites of exposed Cu(II) ions in the smallest cuboctahedral cages are the first, strongest binding sites for D(2) leading to an overall discrimination between the two types of exposed Cu(II) sites at the paddlewheel nodes. Thus, the Cu(II) centers within the cuboctahedral cage are the first sites of D(2) binding with a Cu-D(2) distance of 2.23(1) A.Entities:
Year: 2010 PMID： 20199070 DOI： 10.1021/ja1001407
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419