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Literature DB >> 20184319

Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter.

Xisheng Wang¹, Larry Truesdale, Jin-Quan Yu.

Abstract

A Pd(II)-catalyzed C-H activation/trifluoromethylation of arenes with an electrophilic trifluoromethylation reagent using diverse heterocycle directing groups is reported. The presence of trifluoroacetic acid is crucial for this catalytic reaction.

Entities: Chemical

Mesh：

Substances：

Year: 2010 PMID： 20184319 DOI： 10.1021/ja909522s

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

41 in total

1. Silicon-Tethered Strategies for C-H Functionalization Reactions.

Authors: Marvin Parasram; Vladimir Gevorgyan
Journal: Acc Chem Res Date: 2017-08-03 Impact factor: 22.384

2. Silver-mediated trifluoromethylation of arenes using TMSCF3.

Authors: Yingda Ye; Shin Hee Lee; Melanie S Sanford
Journal: Org Lett Date: 2011-09-20 Impact factor: 6.005

3. Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.

Authors: Nicholas D Ball; J Brannon Gary; Yingda Ye; Melanie S Sanford
Journal: J Am Chem Soc Date: 2011-04-22 Impact factor: 15.419

4. Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I.

Authors: Yingda Ye; Melanie S Sanford
Journal: J Am Chem Soc Date: 2012-05-24 Impact factor: 15.419

Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter.

1. Silicon-Tethered Strategies for C-H Functionalization Reactions.

2. Silver-mediated trifluoromethylation of arenes using TMSCF3.

3. Mechanistic and computational studies of oxidatively-induced aryl-CF3 bond-formation at Pd: rational design of room temperature aryl trifluoromethylation.

4. Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I.

5. Catalysis: Fluorination made easier.

6. Investigations into Transition Metal Catalyzed Arene Trifluoromethylation Reactions.

7. On the mechanism of palladium-catalyzed aromatic C-H oxidation.

8. Innate and guided C-H functionalization logic.

Review 9. Hypervalent Iodine Reagents in High Valent Transition Metal Chemistry.

Review 10. Catalysis for fluorination and trifluoromethylation.