Literature DB >> 20177625

Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.

Kristina L Toups1, Ross A Widenhoefer.   

Abstract

A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic amines in good yield with selective formation of the E-diastereomer.

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Year:  2010        PMID： 20177625      PMCID： PMC2924659          DOI： 10.1039/b925859k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  9 in total

1.  Palladium-Catalyzed Alternating Copolymerization of Alkenes and Carbon Monoxide.

Authors:  Eite Drent; Peter H. M. Budzelaar
Journal:  Chem Rev       Date:  1996-03-28       Impact factor: 60.622

2.  The catalytic hydroamination of alkynes.

Authors:  Frauke Pohlki; Sven Doye
Journal:  Chem Soc Rev       Date:  2003-03       Impact factor: 54.564

Review 3.  Hydroamination: direct addition of amines to alkenes and alkynes.

Authors:  Thomas E Müller; Kai C Hultzsch; Miguel Yus; Francisco Foubelo; Mizuki Tada
Journal:  Chem Rev       Date:  2008-08-26       Impact factor: 60.622

4.  Homogeneous catalytic hydroamination of alkynes and allenes with ammonia.

Authors:  Vincent Lavallo; Guido D Frey; Bruno Donnadieu; Michele Soleilhavoup; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

5.  Platinum-catalyzed intramolecular hydroamination of unactivated olefins with secondary alkylamines.

Authors:  Christopher F Bender; Ross A Widenhoefer
Journal:  J Am Chem Soc       Date:  2005-02-02       Impact factor: 15.419

6.  Imidotitanium complexes as hydroamination catalysts: substantially enhanced reactivity from an unexpected cyclopentadienide/amide ligand exchange.

Authors:  J S Johnson; R G Bergman
Journal:  J Am Chem Soc       Date:  2001-03-28       Impact factor: 15.419

7.  Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines.

Authors:  Xiaoming Zeng; Michele Soleilhavoup; Guy Bertrand
Journal:  Org Lett       Date:  2009-08-06       Impact factor: 6.005

8.  Bite angle effects of diphosphines in C-C and C-X bond forming cross coupling reactions.

Authors:  Mandy-Nicole Birkholz; Zoraida Freixa; Piet W N M van Leeuwen
Journal:  Chem Soc Rev       Date:  2009-02-10       Impact factor: 54.564

9.  Organolanthanide-catalyzed hydroamination.

Authors:  Sukwon Hong; Tobin J Marks
Journal:  Acc Chem Res       Date:  2004-09       Impact factor: 22.384
  9 in total
  4 in total

1.  Gold(I)-Catalyzed Enantioselective Intramolecular Hydroamination of Allenes with Ureas.

Authors:  Hao Li; Seong Du Lee; Ross A Widenhoefer
Journal:  J Organomet Chem       Date:  2011-01-01       Impact factor: 2.369

2.  Gold(I)-catalyzed stereoconvergent, intermolecular enantioselective hydroamination of allenes.

Authors:  Kristina L Butler; Michele Tragni; Ross A Widenhoefer
Journal:  Angew Chem Int Ed Engl       Date:  2012-04-11       Impact factor: 15.336

3.  Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides.

Authors:  Chen Zhang; Shao-Qiao Zhang; Hua-Jun Cai; Dong-Mei Cui
Journal:  Beilstein J Org Chem       Date:  2013-05-29       Impact factor: 2.883

4.  Diastereoselective Pt catalyzed cycloisomerization of polyenes to polycycles.

Authors:  Michael J Geier; Michel R Gagné
Journal:  J Am Chem Soc       Date:  2014-02-13       Impact factor: 15.419
  4 in total

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