Literature DB >> 20177603

Matrix infrared spectra and electronic structure calculations of the first actinide borylene: FB=ThF(2).

Xuefeng Wang1, Björn O Roos, Lester Andrews.   

Abstract

Laser-ablated Th atoms react with BF(3) during condensation in excess argon at 6 K to form the first actinide borylene (FB=ThF(2)) and actinide-boron multiple bond. Three new product absorptions in the B-F and Th-F stretching regions of matrix infrared spectra are assigned to FB=ThF(2) from comparison to theoretically predicted vibrational frequencies.

Entities:  

Year:  2010        PMID： 20177603     DOI： 10.1039/b923195a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Synthesis and reduction chemistry of mixed-Lewis-base-stabilised chloroborylenes.

Authors:  Merle Arrowsmith; Julia I Schweizer; Myron Heinz; Marcel Härterich; Ivo Krummenacher; Max C Holthausen; Holger Braunschweig
Journal:  Chem Sci       Date:  2019-04-08       Impact factor: 9.825

2.  Stabilities, Electronic Structures, and Bonding Properties of Iron Complexes (E1E2)Fe(CO)2(CNArTripp2)2 (E1E2=BF, CO, N2, CN-, or NO+).

Authors:  Gerui Pei; Pei Zhao; Song Xu; Xintian Zhao; Chuncai Kong; Zhimao Yang; Masahiro Ehara; Tao Yang
Journal:  ChemistryOpen       Date:  2020-11-18       Impact factor: 2.630
  2 in total

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