Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Magnesium(I) reduction of benzophenone and anthracene: first structural characterisation of a magnesium ketyl.

Literature DB >> 20162165

Magnesium(I) reduction of benzophenone and anthracene: first structural characterisation of a magnesium ketyl.

Cameron Jones¹, Lucia McDyre, Damien M Murphy, Andreas Stasch.

Abstract

The reductions of benzophenone and anthracene with dimeric magnesium(I) complexes lead to thermally stable magnesium ketyl and magnesium anthracene complexes, respectively; both have been structurally characterised.

Entities: Chemical

Year: 2009 PMID： 20162165 DOI： 10.1039/b922002j

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

Keyword Cloud
Cited

8 in total

1. Persistent Radicals of Self-assembled Benzophenone bis-Urea Macrocycles: Characterization and Application as a Polarizing Agent for Solid-state DNP MAS Spectroscopy.

Authors: Baillie A DeHaven; John T Tokarski; Arthur A Korous; Frederic Mentink-Vigier; Thomas M Makris; Alexander M Brugh; Malcolm D E Forbes; Johan van Tol; Clifford R Bowers; Linda S Shimizu
Journal: Chemistry Date: 2017-05-19 Impact factor: 5.236

2. Synthesis of a stable adduct of dialane(4) (Al2H4) via hydrogenation of a magnesium(I) dimer.

Authors: Simon J Bonyhady; David Collis; Gernot Frenking; Nicole Holzmann; Cameron Jones; Andreas Stasch
Journal: Nat Chem Date: 2010-08-01 Impact factor: 24.427

3. Many Mg-Mg bonds form the core of the Mg₁₆Cp*8Br₄K cluster anion: the key to a reassessment of the Grignard reagent (GR) formation process?

Authors: T Kruczyński; F Henke; M Neumaier; K H Bowen; H Schnöckel
Journal: Chem Sci Date: 2015-11-26 Impact factor: 9.825

4. Synthesis of a Hexameric Magnesium 4-pyridyl Complex with Cyclohexane-like Ring Structure via Reductive C-N Activation.

Authors: Samuel R Lawrence; Matthew de Vere-Tucker; Alexandra M Z Slawin; Andreas Stasch
Journal: Molecules Date: 2021-11-28 Impact factor: 4.411

Magnesium(I) reduction of benzophenone and anthracene: first structural characterisation of a magnesium ketyl.

1. Persistent Radicals of Self-assembled Benzophenone bis-Urea Macrocycles: Characterization and Application as a Polarizing Agent for Solid-state DNP MAS Spectroscopy.

2. Synthesis of a stable adduct of dialane(4) (Al2H4) via hydrogenation of a magnesium(I) dimer.

3. Many Mg-Mg bonds form the core of the Mg₁₆Cp*8Br₄K cluster anion: the key to a reassessment of the Grignard reagent (GR) formation process?

4. Synthesis of a Hexameric Magnesium 4-pyridyl Complex with Cyclohexane-like Ring Structure via Reductive C-N Activation.

5. Cobalt and Iron Stabilized Ketyl, Ketiminyl and Aldiminyl Radical Anions.

6. A Persistent Phosphanyl-Substituted Thioketyl Radical Anion.

7. Umpolung of an Aliphatic Ketone to a Magnesium Ketone-1,2-diide Complex with Vicinal Dianionic Charge.

8. Hydrocarbon-soluble, hexaanionic fulleride complexes of magnesium.