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Literature DB >> 20157897

Nucleophilic phosphinidene complexes: access and applicability.

Halil Aktaş¹, J Chris Slootweg, Koop Lammertsma.

Abstract

Syntheses, properties, and reactivities of nucleophilic phosphinidene complexes [L(n)M=P-R] are reviewed. Emphasis is placed on the electronic tuning of this emerging class of phosphorus reagents, using different ancillary ligands and coordinatively unsaturated transition-metal moieties. The difference in applicability of the established stable 18-electron and transient 16-electron phosphinidenes is addressed.

Entities: Chemical

Mesh：

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Year: 2010 PMID： 20157897 DOI： 10.1002/anie.200905689

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

8 in total

1. Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium(IV).

Authors: Hannah Stafford; Thomas M Rookes; Elizabeth P Wildman; Gábor Balázs; Ashley J Wooles; Manfred Scheer; Stephen T Liddle
Journal: Angew Chem Int Ed Engl Date: 2017-05-26 Impact factor: 15.336

2. Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer.

Authors: Josh Abbenseth; Daniel Delony; Marc C Neben; Christian Würtele; Bas de Bruin; Sven Schneider
Journal: Angew Chem Int Ed Engl Date: 2019-04-01 Impact factor: 15.336

3. Isoselective Polymerization of rac-Lactide by Aluminum Complexes of N-Heterocyclic Carbene-Phosphinidene Adducts.

Authors: Jayeeta Bhattacharjee; Marius Peters; Dirk Bockfeld; Matthias Tamm
Journal: Chemistry Date: 2021-03-03 Impact factor: 5.236

4. Isolable phosphanylidene phosphorane with a sterically accessible two-coordinate phosphorus atom.

Authors: Brian A Surgenor; Michael Bühl; Alexandra M Z Slawin; J Derek Woollins; Petr Kilian
Journal: Angew Chem Int Ed Engl Date: 2012-09-05 Impact factor: 15.336

5. Probing the Origin of Challenge of Realizing Metallaphosphabenzenes: Unfavorable 1,2-Migration in Metallapyridines Becomes Feasible in Metallaphosphabenzenes.

Authors: Jingjing Wu; Yulei Hao; Jun Zhu
Journal: Sci Rep Date: 2016-06-24 Impact factor: 4.379

Nucleophilic phosphinidene complexes: access and applicability.

1. Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium(IV).

2. Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer.

3. Isoselective Polymerization of rac-Lactide by Aluminum Complexes of N-Heterocyclic Carbene-Phosphinidene Adducts.

4. Isolable phosphanylidene phosphorane with a sterically accessible two-coordinate phosphorus atom.

5. Probing the Origin of Challenge of Realizing Metallaphosphabenzenes: Unfavorable 1,2-Migration in Metallapyridines Becomes Feasible in Metallaphosphabenzenes.

6. Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes.

7. Isolation of Cyclic(Alkyl)(Amino) Carbene-Bismuthinidene Mediated by a Beryllium(0) Complex.

8. Rhodium and Iridium Complexes of Anionic Thione and Selone Ligands Derived from Anionic N-Heterocyclic Carbenes.