| Literature DB >> 20136154 |
Arnaud Stévenin1, François-Didier Boyer, Jean-Marie Beau.
Abstract
The oxidative cleavage of 4,6-O-benzylidene acetals of glycopyranosides using dimethyldioxirane (DMDO) leads to the corresponding hydroxy-benzoates in excellent yields. With a proper choice of the neighboring protecting groups, this oxidative fragmentation provides the 6- or 4-hydroxyl derivatives in a highly regioselective manner.Entities:
Year: 2010 PMID： 20136154 DOI： 10.1021/jo9026098
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354