Literature DB >> 20126709

Unusual reactivities of N-heterocyclic carbenes upon coordination to the platinum(II)-dimethyl moiety.

George C Fortman1, Natalie M Scott, Anthony Linden, Edwin D Stevens, Reto Dorta, Steven P Nolan.   

Abstract

Unsaturated NHCs of varying steric bulk undergo a series of unusual oxidative addition and reductive elimination processes upon binding to the Pt(Me)(2) fragment.

Entities:  

Year:  2010        PMID： 20126709     DOI： 10.1039/b920482b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization.

Authors:  Zhenwu Ouyang; Jingzhen Du; Lei Wang; Jared L Kneebone; Michael L Neidig; Liang Deng
Journal:  Inorg Chem       Date:  2015-08-14       Impact factor: 5.165

2.  Bite-angle bending as a key for understanding group-10 metal reactivity of d10-[M(NHC)2] complexes with sterically modest NHC ligands.

Authors:  Florian Hering; Jörn Nitsch; Ursula Paul; Andreas Steffen; F Matthias Bickelhaupt; Udo Radius
Journal:  Chem Sci       Date:  2014-12-03       Impact factor: 9.825

3.  Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SF3 , S(=O)F and Fluorido Complexes.

Authors:  Dilcan Dirican; Maria Talavera; Thomas Braun
Journal:  Chemistry       Date:  2021-10-29       Impact factor: 5.020
  3 in total

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