| Literature DB >> 20126703 |
Noureddine Ajellal1, Guillaume Durieux, Laurent Delevoye, Grégory Tricot, Christophe Dujardin, Christophe M Thomas, Régis M Gauvin.
Abstract
Grafting of [Ln(BH(4))(3)(THF)(3)] (Ln = La, Nd) onto silica affords materials containing well-identified bis(borohydride) surface species. The neodymium-decorated silica converts the beta-butyrolactone monomer into highly isotactic poly(beta-hydroxybutyrate). Under similar conditions, the molecular precursor gives rise to an atactic polymer.Entities:
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Year: 2010 PMID： 20126703 DOI： 10.1039/b923546a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222