Literature DB >> 20126701

Lewis acid mediated P-P bond hydrogenation and hydrosilylation.

Stephen J Geier1, Douglas W Stephan.   

Abstract

The reaction of H(2), R(3)SiH or R(2)SiH(2) with P(5)Ph(5) in the presence of stoichiometric B(C(6)F(5))(3) results in excellent yields of the phosphine-borane adducts (PhPH(2))B(C(6)F(5))(3), ((R(3)Si)PhPH)B(C(6)F(5))(3) and ((R(2)SiH)PhPH)B(C(6)F(5))(3), respectively.

Entities:  

Year:  2010        PMID: 20126701     DOI: 10.1039/b925126j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Exploring the Reactivity of Unsymmetrical Diphosphanes toward Heterocumulenes: Access to Phosphanyl and Phosphoryl Derivatives of Amides, Imines, and Iminoamides.

Authors:  Natalia Szynkiewicz; Jarosław Chojnacki; Rafał Grubba
Journal:  Inorg Chem       Date:  2022-06-14       Impact factor: 5.436

  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.