Literature DB >> 20112945

Scalable synthesis of cryptophane-1.1.1 and its functionalization.

Ténin Traoré1, Léa Delacour, Sébastien Garcia-Argote, Patrick Berthault, Jean-Christophe Cintrat, Bernard Rousseau.   

Abstract

Cryptophanes, cage molecules for which xenon exhibits a high affinity, are good candidates for xenon biosensing. Cryptophane-1.1.1 (1) exhibits the highest binding constant for xenon encapsulation in organic solution determined to date. This property suggests that the cryptophane-1.1.1 core (1) is optimal for sensing applications. A high-yielding scalable synthesis of compound 1 is reported as well as an easy way to functionalize it.

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Year:  2010        PMID: 20112945     DOI: 10.1021/ol902952h

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Shorter synthesis of trifunctionalized cryptophane-A derivatives.

Authors:  Olena Taratula; P Aru Hill; Yubin Bai; Najat S Khan; Ivan J Dmochowski
Journal:  Org Lett       Date:  2011-02-18       Impact factor: 6.005

2.  Cryptophane-xenon complexes for 129Xe MRI applications.

Authors:  Serge D Zemerov; Ivan J Dmochowski
Journal:  RSC Adv       Date:  2021-02-17       Impact factor: 3.361

  2 in total

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