Literature DB >> 20108936

Arisandilactone A, a new triterpenoid from the fruits of Schisandra arisanensis.

Yuan-Bin Cheng1, Tzu-Ching Liao, I-Wen Lo, Yu-Chen Chen, Yuh-Chi Kuo, Shun-Ying Chen, Ching-Te Chien, Ya-Ching Shen.   

Abstract

A phytochemical investigation of the fruits of Schisandra arisanensis has yielded a novel triterpenoid, arisandilactone A (1). Compound 1 has an unprecedented skeleton having a 5/5/7/5/8/5-fused hexacyclic ring system. The structure of 1 was elucidated by spectroscopic methods, especially 2D NMR techniques (COSY, HMQC, HMBC, and NOESY) and was confirmed by X-ray crystallographic analysis. A plausible biosynthetic pathway for 1 is also discussed.

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Year:  2010        PMID: 20108936     DOI: 10.1021/ol100024r

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Biomimetically inspired asymmetric total synthesis of (+)-19-dehydroxyl arisandilactone A.

Authors:  Yi-Xin Han; Yan-Long Jiang; Yong Li; Hai-Xin Yu; Bing-Qi Tong; Zhe Niu; Shi-Jie Zhou; Song Liu; Yu Lan; Jia-Hua Chen; Zhen Yang
Journal:  Nat Commun       Date:  2017-01-31       Impact factor: 14.919

  1 in total

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