Literature DB >> 20107650

Convenient access to the anhydrous thorium tetrachloride complexes ThCl(4)(DME)(2), ThCl(4)(1,4-dioxane)(2) and ThCl(4)(THF)(3.5) using commercially available and inexpensive starting materials.

Thibault Cantat1, Brian L Scott, Jaqueline L Kiplinger.   

Abstract

Anhydrous thorium tetrachloride complexes ThCl(4)(DME)(2), ThCl(4)(1,4-dioxane)(2), and ThCl(4)(THF)(3.5) have been easily accessed from inexpensive, commercially available reagents under mild conditions and serve as excellent precursors to a variety of thorium(iv) halide, alkoxide, amide and organometallic compounds.

Entities:  

Year:  2010        PMID： 20107650     DOI： 10.1039/b923558b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

1.  How 5 f Electron Polarisability Drives Covalency and Selectivity in Actinide N-Donor Complexes.

Authors:  Luisa Köhler; Michael Patzschke; Moritz Schmidt; Thorsten Stumpf; Juliane März
Journal:  Chemistry       Date:  2021-12-02       Impact factor: 5.020

2.  The ketimide ligand is not just an inert spectator: heteroallene insertion reactivity of an actinide-ketimide linkage in a thorium carbene amide ketimide complex.

Authors:  Erli Lu; William Lewis; Alexander J Blake; Stephen T Liddle
Journal:  Angew Chem Int Ed Engl       Date:  2014-07-07       Impact factor: 15.336

3.  Multi-electron reduction of sulfur and carbon disulfide using binuclear uranium(iii) borohydride complexes.

Authors:  Polly L Arnold; Charlotte J Stevens; Nicola L Bell; Rianne M Lord; Jonathan M Goldberg; Gary S Nichol; Jason B Love
Journal:  Chem Sci       Date:  2017-03-10       Impact factor: 9.825

4.  Use of 15N NMR spectroscopy to probe covalency in a thorium nitride.

Authors:  Selena L Staun; Dumitru-Claudiu Sergentu; Guang Wu; Jochen Autschbach; Trevor W Hayton
Journal:  Chem Sci       Date:  2019-06-04       Impact factor: 9.825

5.  Bonding Trends in Tetravalent Th-Pu Monosalen Complexes.

Authors:  Thomas Radoske; Juliane März; Michael Patzschke; Peter Kaden; Olaf Walter; Moritz Schmidt; Thorsten Stumpf
Journal:  Chemistry       Date:  2020-11-09       Impact factor: 5.236

6.  Covalent bond shortening and distortion induced by pressurization of thorium, uranium, and neptunium tetrakis aryloxides.

Authors:  Jacob J Shephard; Victoria E J Berryman; Tatsumi Ochiai; Olaf Walter; Amy N Price; Mark R Warren; Polly L Arnold; Nikolas Kaltsoyannis; Simon Parsons
Journal:  Nat Commun       Date:  2022-10-07       Impact factor: 17.694

7.  Heteroleptic actinocenes: a thorium(iv)-cyclobutadienyl-cyclooctatetraenyl-di-potassium-cyclooctatetraenyl complex.

Authors:  Josef T Boronski; Ashley J Wooles; Stephen T Liddle
Journal:  Chem Sci       Date:  2020-06-10       Impact factor: 9.825

8.  Thorium-ligand multiple bonds via reductive deprotection of a trityl group.

Authors:  Danil E Smiles; Guang Wu; Nikolas Kaltsoyannis; Trevor W Hayton
Journal:  Chem Sci       Date:  2015-04-30       Impact factor: 9.825
  8 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.