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Literature DB >> 20088527

Room temperature reduction of CO2 to methanol by Al-based frustrated Lewis pairs and ammonia borane.

Abstract

AlX(3) (X = Cl or Br) and PMes(3) (Mes = 2,4,6-C(6)H(2)Me(3)) react to form weak Lewis adducts but also react with CO(2) to give Mes(3)P(CO(2))(AlX(3))(2) (X = Cl; Br). These species react rapidly with excess ammonia borane at room temperature to give CH(3)OH upon quenching with water.

Entities: Chemical Gene

Year: 2010 PMID： 20088527 DOI： 10.1021/ja9104792

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

16 in total

1. Investigation of main group promoted carbon dioxide reduction.

Authors: Brena L Thompson; Zachariah M Heiden
Journal: Tetrahedron Date: 2019-02-15 Impact factor: 2.457

Review 2. Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation.

Authors: Aaron M Appel; John E Bercaw; Andrew B Bocarsly; Holger Dobbek; Daniel L DuBois; Michel Dupuis; James G Ferry; Etsuko Fujita; Russ Hille; Paul J A Kenis; Cheryl A Kerfeld; Robert H Morris; Charles H F Peden; Archie R Portis; Stephen W Ragsdale; Thomas B Rauchfuss; Joost N H Reek; Lance C Seefeldt; Rudolf K Thauer; Grover L Waldrop
Journal: Chem Rev Date: 2013-06-14 Impact factor: 60.622

Room temperature reduction of CO2 to methanol by Al-based frustrated Lewis pairs and ammonia borane.

1. Investigation of main group promoted carbon dioxide reduction.

Review 2. Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation.

3. Halogenated triphenylgallium and -indium in frustrated Lewis pair activations and hydrogenation catalysis.

4. Carbon dioxide reduction by an Al-O-P frustrated Lewis pair.

5. Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH₂SiMe₃)₃-Induced C-H Functionalizations.

6. Quantifying the efficiency of CO₂ capture by Lewis pairs.

7. Modeling Adsorption and Optical Properties for the Design of CO₂ Photocatalytic Metal-Organic Frameworks.

8. Tri-insertion with dearomatization of terminal arylalkynes using a carborane based frustrated Lewis pair template.

9. Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.

10. Direct Photochemical C-H Carboxylation of Aromatic Diamines with CO₂ under Electron-Donor- and Base-free Conditions.