| Literature DB >> 20088525 |
Teresa de Haro1, Cristina Nevado.
Abstract
A novel gold-catalyzed ethynylation of aromatic rings with electron-deficient alkynes via gold catalyzed C-H activation of both C(sp)-H and C(sp(2))-H bonds has been developed. This transformation provides aromatic propiolates difficult to prepare by other methods, highlighting the synthetic potential of gold chemistry.Entities:
Year: 2010 PMID: 20088525 DOI: 10.1021/ja909726h
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419