Literature DB >> 20088525

Gold-catalyzed ethynylation of arenes.

Teresa de Haro1, Cristina Nevado.   

Abstract

A novel gold-catalyzed ethynylation of aromatic rings with electron-deficient alkynes via gold catalyzed C-H activation of both C(sp)-H and C(sp(2))-H bonds has been developed. This transformation provides aromatic propiolates difficult to prepare by other methods, highlighting the synthetic potential of gold chemistry.

Entities:  

Year:  2010        PMID: 20088525     DOI: 10.1021/ja909726h

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  28 in total

Review 1.  Hypervalent Iodine Reagents in High Valent Transition Metal Chemistry.

Authors:  Felipe Cesar Sousa E Silva; Anthony F Tierno; Sarah E Wengryniuk
Journal:  Molecules       Date:  2017-05-12       Impact factor: 4.411

2.  Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C-H Bonds by Silver-Mediated C-H Activation: A Synthetic and Mechanistic Investigation.

Authors:  Sarah Yunmi Lee; John F Hartwig
Journal:  J Am Chem Soc       Date:  2016-11-14       Impact factor: 15.419

3.  Umpolung reactivity of indole through gold catalysis.

Authors:  Biao Lu; Yingdong Luo; Lianzhu Liu; Longwu Ye; Yanzhao Wang; Liming Zhang
Journal:  Angew Chem Int Ed Engl       Date:  2011-07-14       Impact factor: 15.336

4.  Facilitating Gold Redox Catalysis with Electrochemistry: An Efficient Chemical-Oxidant-Free Approach.

Authors:  Xiaohan Ye; Pengyi Zhao; Shuyao Zhang; Yanbin Zhang; Qilin Wang; Chuan Shan; Lukasz Wojtas; Hao Guo; Hao Chen; Xiaodong Shi
Journal:  Angew Chem Int Ed Engl       Date:  2019-09-04       Impact factor: 15.336

Review 5.  Bystanding F+ oxidants enable selective reductive elimination from high-valent metal centers in catalysis.

Authors:  Keary M Engle; Tian-Sheng Mei; Xisheng Wang; Jin-Quan Yu
Journal:  Angew Chem Int Ed Engl       Date:  2011-01-24       Impact factor: 15.336

6.  Ligand-Promoted meta-C-H Amination and Alkynylation.

Authors:  Peng Wang; Gen-Cheng Li; Pankaj Jain; Marcus E Farmer; Jian He; Peng-Xiang Shen; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2016-10-13       Impact factor: 15.419

7.  Stable Au(I) catalysts for oxidant-free C-H Functionalization with Iodoarenes.

Authors:  R Tyler Mertens; Charles E Greif; James T Coogle; Gilles Berger; Sean Parkin; Mark D Watson; Samuel G Awuah
Journal:  J Catal       Date:  2022-02-28       Impact factor: 7.920

8.  Chiral Hemilabile P,N-Ligand-Assisted Gold Redox Catalysis for Enantioselective Alkene Aminoarylation.

Authors:  Xiaohan Ye; Chenhuan Wang; Shuyao Zhang; Qi Tang; Lukasz Wojtas; Minyong Li; Xiaodong Shi
Journal:  Chemistry       Date:  2022-05-11       Impact factor: 5.020

9.  One-pot gold-catalyzed synthesis of 3-silylethynyl indoles from unprotected o-alkynylanilines.

Authors:  Jonathan P Brand; Clara Chevalley; Jérôme Waser
Journal:  Beilstein J Org Chem       Date:  2011-05-04       Impact factor: 2.883

Review 10.  Homogeneous Gold-Catalyzed Oxidation Reactions.

Authors:  Zhitong Zheng; Xu Ma; Xinpeng Cheng; Ke Zhao; Kaylaa Gutman; Tianyou Li; Liming Zhang
Journal:  Chem Rev       Date:  2021-02-16       Impact factor: 72.087

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