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Literature DB >> 20087518

BN benzonitrile: an electron-deficient 1,2-dihydro-1,2-azaborine featuring linkage isomerism.

Adam J V Marwitz¹, Sean P McClintock, Lev N Zakharov, Shih-Yuan Liu.

Abstract

BN Benzonitrile 2, a 1,2-dihydro-1,2-azaborine bearing an electron-withdrawing boron substituent was prepared and characterized, and its coordination chemistry investigated; reactivity studies revealed that BN benzonitrile 2 undergoes BCN-BNC linkage isomerism upon coordination to Cr(CO)(5).

Entities: Chemical

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Substances：

Year: 2009 PMID： 20087518 DOI： 10.1039/b919632c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

8 in total

Review 1. Recent advances in azaborine chemistry.

Authors: Patrick G Campbell; Adam J V Marwitz; Shih-Yuan Liu
Journal: Angew Chem Int Ed Engl Date: 2012-05-29 Impact factor: 15.336

2. Nucleophilic aromatic substitution reactions of 1,2-dihydro-1,2-azaborine.

Authors: Ashley N Lamm; Edward B Garner; David A Dixon; Shih-Yuan Liu
Journal: Angew Chem Int Ed Engl Date: 2011-07-12 Impact factor: 15.336

3. Negishi Cross-Coupling Is Compatible with a Reactive B-Cl Bond: Development of a Versatile Late-Stage Functionalization of 1,2-Azaborines and Its Application to the Synthesis of New BN Isosteres of Naphthalene and Indenyl.

Authors: Alec N Brown; Bo Li; Shih-Yuan Liu
Journal: J Am Chem Soc Date: 2015-07-09 Impact factor: 15.419

BN benzonitrile: an electron-deficient 1,2-dihydro-1,2-azaborine featuring linkage isomerism.

Review 1. Recent advances in azaborine chemistry.

2. Nucleophilic aromatic substitution reactions of 1,2-dihydro-1,2-azaborine.

3. Negishi Cross-Coupling Is Compatible with a Reactive B-Cl Bond: Development of a Versatile Late-Stage Functionalization of 1,2-Azaborines and Its Application to the Synthesis of New BN Isosteres of Naphthalene and Indenyl.

4. Rhodium-catalyzed boron arylation of 1,2-azaborines.

5. Boron-substituted 1,3-dihydro-1,3-azaborines: synthesis, structure, and evaluation of aromaticity.

6. Thermodynamically Controlled, Dynamic Binding of Diols to a 1,2-BN Cyclohexane Derivative.

7. 1,2-Azaborine cations.

8. A 1,3-dihydro-1,3-azaborine debuts.