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Literature DB >> 20087497

On the dissolution of non-metallic solid elements (sulfur, selenium, tellurium and phosphorus) in ionic liquids.

Eva Boros¹, Martyn J Earle, Manuela A Gîlea, Andreas Metlen, Anja-Verena Mudring, Franziska Rieger, Allan J Robertson, Kenneth R Seddon, Alina A Tomaszowska, Lev Trusov, Joseph S Vyle.

Abstract

Ionic liquids are shown to be good solvents for elemental sulfur, selenium, phosphorus and tellurium, and can be designed to maximise the solubility of these elements. The presence of the [S(3)](*-) radical anion in diluted solutions of sulfur in some ionic liquids has been confirmed, and is the origin of their intense blue colour (cf. lapis lazuli).

Entities: Chemical

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Year: 2009 PMID： 20087497 DOI： 10.1039/b910469k

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

4 in total

1. The use of elemental sulfur as an alternative feedstock for polymeric materials.

Authors: Woo Jin Chung; Jared J Griebel; Eui Tae Kim; Hyunsik Yoon; Adam G Simmonds; Hyun Jun Ji; Philip T Dirlam; Richard S Glass; Jeong Jae Wie; Ngoc A Nguyen; Brett W Guralnick; Jungjin Park; Arpád Somogyi; Patrick Theato; Michael E Mackay; Yung-Eun Sung; Kookheon Char; Jeffrey Pyun
Journal: Nat Chem Date: 2013-04-14 Impact factor: 24.427

On the dissolution of non-metallic solid elements (sulfur, selenium, tellurium and phosphorus) in ionic liquids.

1. The use of elemental sulfur as an alternative feedstock for polymeric materials.

Review 2. Heavy Chalcogenide-Based Ionic Liquids in Syntheses of Metal Chalcogenide Materials near Room Temperature.

3. Coexistence of Tellurium Cations and Anions in Phosphonium-Based Ionic Liquids.

4. Isolation and Properties of the Long Elusive Deep Blue Soluble [K₃ {(N^t Bu)₃ S}₂ ]^. Cage Radical.

On the dissolution of non-metallic solid elements (sulfur, selenium, tellurium and phosphorus) in ionic liquids.

1. The use of elemental sulfur as an alternative feedstock for polymeric materials.

Review 2. Heavy Chalcogenide-Based Ionic Liquids in Syntheses of Metal Chalcogenide Materials near Room Temperature.

3. Coexistence of Tellurium Cations and Anions in Phosphonium-Based Ionic Liquids.

4. Isolation and Properties of the Long Elusive Deep Blue Soluble [K3 {(Nt Bu)3 S}2 ]. Cage Radical.

4. Isolation and Properties of the Long Elusive Deep Blue Soluble [K₃ {(N^t Bu)₃ S}₂ ]^. Cage Radical.