Literature DB >> 20085264

Mechanism of water oxidation by single-site ruthenium complex catalysts.

Javier J Concepcion1, Ming-Kang Tsai, James T Muckerman, Thomas J Meyer.   

Abstract

The mechanism of Ce(IV) water oxidation catalyzed by [Ru(tpy)(bpm)(OH(2))](2+) (tpy = 2,2':6',2''-terpyridine; bpm = 2,2'-bipyrimidine) and related single-site catalysts has been determined by a combination of mixing and stopped-flow experiments with spectrophotometric monitoring. The mechanism features O---O coupling by water attack on Ru(V)=O(3+) and three peroxidic intermediates that have been characterized by a combination of spectroscopy and DFT calculations.

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Year:  2010        PMID： 20085264     DOI： 10.1021/ja904906v

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  21 in total

Review 1.  Thermochemistry of proton-coupled electron transfer reagents and its implications.

Authors:  Jeffrey J Warren; Tristan A Tronic; James M Mayer
Journal:  Chem Rev       Date:  2010-10-06       Impact factor: 60.622

2.  Theoretical study of catalytic mechanism for single-site water oxidation process.

Authors:  Xiangsong Lin; Xiangqian Hu; Javier J Concepcion; Zuofeng Chen; Shubin Liu; Thomas J Meyer; Weitao Yang
Journal:  Proc Natl Acad Sci U S A       Date:  2012-05-21       Impact factor: 11.205

3.  Base-enhanced catalytic water oxidation by a carboxylate-bipyridine Ru(II) complex.

Authors:  Na Song; Javier J Concepcion; Robert A Binstead; Jennifer A Rudd; Aaron K Vannucci; Christopher J Dares; Michael K Coggins; Thomas J Meyer
Journal:  Proc Natl Acad Sci U S A       Date:  2015-04-06       Impact factor: 11.205

4.  Isolation and Study of Ruthenium-Cobalt Oxo Cubanes Bearing a High-Valent, Terminal RuV-Oxo with Significant Oxyl Radical Character.

Authors:  Jaruwan Amtawong; David Balcells; Jarett Wilcoxen; Rex C Handford; Naomi Biggins; Andy I Nguyen; R David Britt; T Don Tilley
Journal:  J Am Chem Soc       Date:  2019-12-05       Impact factor: 15.419

5.  Concerted O atom-proton transfer in the O-O bond forming step in water oxidation.

Authors:  Zuofeng Chen; Javier J Concepcion; Xiangqian Hu; Weitao Yang; Paul G Hoertz; Thomas J Meyer
Journal:  Proc Natl Acad Sci U S A       Date:  2010-04-01       Impact factor: 11.205

6.  Water-oxidation catalysis by manganese in a geochemical-like cycle.

Authors:  Rosalie K Hocking; Robin Brimblecombe; Lan-Yun Chang; Archana Singh; Mun Hon Cheah; Chris Glover; William H Casey; Leone Spiccia
Journal:  Nat Chem       Date:  2011-05-15       Impact factor: 24.427

7.  Splitting CO2 into CO and O2 by a single catalyst.

Authors:  Zuofeng Chen; Javier J Concepcion; M Kyle Brennaman; Peng Kang; Michael R Norris; Paul G Hoertz; Thomas J Meyer
Journal:  Proc Natl Acad Sci U S A       Date:  2012-06-08       Impact factor: 11.205

8.  Electrode-assisted catalytic water oxidation by a flavin derivative.

Authors:  Ekaterina Mirzakulova; Renat Khatmullin; Janitha Walpita; Thomas Corrigan; Nella M Vargas-Barbosa; Shubham Vyas; Shameema Oottikkal; Samuel F Manzer; Christopher M Hadad; Ksenija D Glusac
Journal:  Nat Chem       Date:  2012-08-26       Impact factor: 24.427

9.  Probing the Viability of Oxo-Coupling Pathways in Iridium-Catalyzed Oxygen Evolution.

Authors:  Jonathan Graeupner; Ulrich Hintermair; Daria L Huang; Julianne M Thomsen; Mike Takase; Jesús Campos; Sara M Hashmi; Menachem Elimelech; Gary W Brudvig; Robert H Crabtree
Journal:  Organometallics       Date:  2013-10-14       Impact factor: 3.876

10.  Study on the substitution effects of zinc benzoate terpyridine complexes on photoluminescence, antiproliferative potential and DNA binding properties.

Authors:  Jinzhang Jiang; Jiahe Li; Chengzhang Liu; Rongping Liu; Xing Liang; Yanling Zhou; Lixia Pan; Hailan Chen; Zhen Ma
Journal:  J Biol Inorg Chem       Date:  2020-02-28       Impact factor: 3.358
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