Anodic formation of thick anatase TiO2 mesosponge layers for high-efficiency photocatalysis.

We report a process for the fabrication of an anatase TiO(2) mesosponge (TMS) layer by an optimized Ti anodization process in a hot glycerol electrolyte followed by a suitable etching process. Such layers can easily be grown to >10 microm thickness and have regular channels and structural features in the 5-20 nm range. The layers show high photocatalytic activity and are mechanically very robust. The layers therefore open new pathways to the wide field of TiO(2)(anatase) applications.