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Literature DB >> 20067255

C-H bond activation in transition metal species from a computational perspective.

David Balcells¹, Eric Clot, Odile Eisenstein.

Abstract

Entities: Chemical

Mesh：

Substances：

Year: 2010 PMID： 20067255 DOI： 10.1021/cr900315k

Source DB: PubMed Journal: Chem Rev ISSN： 0009-2665 Impact factor: 60.622

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65 in total

1. Exchange-enhanced reactivity in bond activation by metal-oxo enzymes and synthetic reagents.

Authors: Sason Shaik; Hui Chen; Deepa Janardanan
Journal: Nat Chem Date: 2010-12-15 Impact factor: 24.427

2. O-H hydrogen bonding promotes H-atom transfer from α C-H bonds for C-alkylation of alcohols.

Authors: Jenna L Jeffrey; Jack A Terrett; David W C MacMillan
Journal: Science Date: 2015-08-27 Impact factor: 47.728

Review 3. Proton-coupled electron transfer.

Authors: My Hang V Huynh; Thomas J Meyer
Journal: Chem Rev Date: 2007-11 Impact factor: 60.622

4. Understanding the factors affecting the activation of alkane by Cp'Rh(CO)2 (Cp' = Cp or Cp*).

Authors: Michael W George; Michael B Hall; Omar S Jina; Peter Portius; Xue-Zhong Sun; Michael Towrie; Hong Wu; Xinzheng Yang; Snezana D Zaric
Journal: Proc Natl Acad Sci U S A Date: 2010-11-03 Impact factor: 11.205

5. Palladium-Catalyzed Transformations of Alkyl C-H Bonds.

Authors: Jian He; Masayuki Wasa; Kelvin S L Chan; Qian Shao; Jin-Quan Yu
Journal: Chem Rev Date: 2016-12-02 Impact factor: 60.622

6. Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control of C(sp²)-H Oxidative Addition Results in ortho-to-Fluorine Selectivity.

Authors: Tyler P Pabst; Jennifer V Obligacion; Étienne Rochette; Iraklis Pappas; Paul J Chirik
Journal: J Am Chem Soc Date: 2019-09-16 Impact factor: 15.419

C-H bond activation in transition metal species from a computational perspective.

1. Exchange-enhanced reactivity in bond activation by metal-oxo enzymes and synthetic reagents.

2. O-H hydrogen bonding promotes H-atom transfer from α C-H bonds for C-alkylation of alcohols.

Review 3. Proton-coupled electron transfer.

4. Understanding the factors affecting the activation of alkane by Cp'Rh(CO)2 (Cp' = Cp or Cp*).

5. Palladium-Catalyzed Transformations of Alkyl C-H Bonds.

6. Cobalt-Catalyzed Borylation of Fluorinated Arenes: Thermodynamic Control of C(sp²)-H Oxidative Addition Results in ortho-to-Fluorine Selectivity.

7. Palladium-Catalyzed Chemoselective Activation of sp³ vs sp² C-H Bonds: Oxidative Coupling To Form Quaternary Centers.

Review 8. If C-H bonds could talk: selective C-H bond oxidation.

9. Surprisingly Facile C-H Activation in the Course of Oxime-Directed Catalytic Asymmetric Hydroboration.

10. Inverting Steric Effects: Using "Attractive" Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer.