Literature DB >> 20062864

Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides.

Devendra J Vyas1, Martin Oestreich.   

Abstract

An unprecedented copper-catalysed allylic transposition enables the regioselective synthesis of branched allylic silanes from linear allylic halides through direct C-Si bond formation.

Entities:  

Year:  2009        PMID： 20062864     DOI： 10.1039/b920793g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Direct synthesis and applications of solid silylzinc reagents.

Authors:  Revathi Chandrasekaran; Feba Thomas Pulikkottil; Krishna Suresh Elama; Ramesh Rasappan
Journal:  Chem Sci       Date:  2021-11-30       Impact factor: 9.825

2.  Sodium silylsilanolate as a precursor of silylcopper species.

Authors:  Hiroki Yamagishi; Kenshiro Hitoshio; Jun Shimokawa; Hideki Yorimitsu
Journal:  Chem Sci       Date:  2022-03-21       Impact factor: 9.825
  2 in total

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