Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Efficient and selective epoxidation of styrene with TBHP catalyzed by Au(25) clusters on hydroxyapatite.

Literature DB >> 20062858

Efficient and selective epoxidation of styrene with TBHP catalyzed by Au(25) clusters on hydroxyapatite.

Yongmei Liu¹, Hironori Tsunoyama, Tomoki Akita, Tatsuya Tsukuda.

Abstract

Au(25) clusters supported on hydroxyapatite oxidized styrene in toluene with 100% conversion and 92% selectivity to the epoxide, under optimum conditions and using anhydrous tert-butyl hydroperoxide (TBHP) as an oxidant.

Entities: Chemical

Year: 2009 PMID： 20062858 DOI： 10.1039/b921082b

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

Keyword Cloud
Cited

8 in total

1. Quantum size effects in ambient CO oxidation catalysed by ligand-protected gold clusters.

Authors: Olga Lopez-Acevedo; Katarzyna A Kacprzak; Jaakko Akola; Hannu Häkkinen
Journal: Nat Chem Date: 2010-03-24 Impact factor: 24.427

Review 2. Cancer nanotechnology: emerging role of gold nanoconjugates.

Authors: Rachel A Kudgus; Resham Bhattacharya; Priyabrata Mukherjee
Journal: Anticancer Agents Med Chem Date: 2011-12 Impact factor: 2.505

3. Exceptional oxidation activity with size-controlled supported gold clusters of low atomicity.

Authors: Avelino Corma; Patricia Concepción; Mercedes Boronat; Maria J Sabater; Javier Navas; Miguel José Yacaman; Eduardo Larios; Alvaro Posadas; M Arturo López-Quintela; David Buceta; Ernest Mendoza; Gemma Guilera; Alvaro Mayoral
Journal: Nat Chem Date: 2013-08-04 Impact factor: 24.427

Efficient and selective epoxidation of styrene with TBHP catalyzed by Au(25) clusters on hydroxyapatite.

1. Quantum size effects in ambient CO oxidation catalysed by ligand-protected gold clusters.

Review 2. Cancer nanotechnology: emerging role of gold nanoconjugates.

3. Exceptional oxidation activity with size-controlled supported gold clusters of low atomicity.

4. Size and shape of nanoclusters: single-shot imaging approach.

5. Controlled reduction for size selective synthesis of thiolate-protected gold nanoclusters Aun(n = 20, 24, 39, 40).

Review 6. Activation of atom-precise clusters for catalysis.

7. Ligand-free gold nanoclusters confined in mesoporous silica nanoparticles for styrene epoxidation.

8. Au25 clusters as electron-transfer catalysts induced the intramolecular cascade reaction of 2-nitrobenzonitrile.