Literature DB >> 20052978

Enantioselective synthesis of allylic esters via asymmetric allylic substitution with metal carboxylates using planar-chiral cyclopentadienyl ruthenium catalysts.

Naoya Kanbayashi1, Kiyotaka Onitsuka.   

Abstract

An asymmetric allylic substitution with sodium carboxylate using a planar-chiral cyclopentadienyl ruthenium complex has been developed. Optically active allylic esters were prepared in good yields with high regio- and enantioselectivities.

Entities:  

Year:  2010        PMID： 20052978     DOI： 10.1021/ja908456b

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Catalytic asymmetric synthesis of chiral allylic esters.

Authors:  Stefan F Kirsch; Larry E Overman
Journal:  J Am Chem Soc       Date:  2005-03-09       Impact factor: 15.419

2.  Chiral cyclopentadienylruthenium sulfoxide catalysts for asymmetric redox bicycloisomerization.

Authors:  Barry M Trost; Michael C Ryan; Meera Rao
Journal:  Beilstein J Org Chem       Date:  2016-06-07       Impact factor: 2.883

3.  Catalytic asymmetric synthesis of geminal-dicarboxylates.

Authors:  Nisha Mistry; Stephen P Fletcher
Journal:  Chem Sci       Date:  2018-06-28       Impact factor: 9.825

4.  Enantio- and regioselective asymmetric allylic substitution using a chiral aminophosphinite ruthenium complex: an experimental and theoretical investigation.

Authors:  Rajesh K Jena; Dhiraj Das
Journal:  RSC Adv       Date:  2021-12-09       Impact factor: 4.036
  4 in total

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