Literature DB >> 20050655

Highly enantioselective intramolecular copper catalyzed C-H insertion reactions of alpha-diazosulfones.

Christopher J Flynn1, Curtis J Elcoate, Simon E Lawrence, Anita R Maguire.   

Abstract

Excellent enantiocontrol (up to 98% ee) is achieved in copper catalyzed C-H insertions of alpha-diazosulfones to form thiopyrans, with up to 60% ee in C-H insertions leading to sulfolanes.

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Year:  2010        PMID： 20050655     DOI： 10.1021/ja909713a

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  8 in total

1.  Further Developments and Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis.

Authors:  Robert Connon; Brendan Roche; Balaji V Rokade; Patrick J Guiry
Journal:  Chem Rev       Date:  2021-05-21       Impact factor: 60.622

2.  SYNTHETICALLY USEFUL INTERMEDIATES BY DIAZOSULFONE AND SULFONATE C-H INSERTION.

Authors:  Duminda S Liyanage; Christian S Jungong; Alexei V Novikov
Journal:  Synth Commun       Date:  2015-01-17       Impact factor: 2.007

Review 3.  Recent Advances in Catalytic Alkyne Transformation via Copper Carbene Intermediates.

Authors:  Kuiyong Dong; Mengting Liu; Xinfang Xu
Journal:  Molecules       Date:  2022-05-11       Impact factor: 4.927

4.  Asymmetric synthesis of neolignans (-)-epi-conocarpan and (+)-conocarpan via Rh(II)-catalyzed C-H insertion process and revision of the absolute configuration of (-)-epi-conocarpan.

Authors:  Yoshihiro Natori; Hideyuki Tsutsui; Naoki Sato; Seiichi Nakamura; Hisanori Nambu; Motoo Shiro; Shunichi Hashimoto
Journal:  J Org Chem       Date:  2009-06-05       Impact factor: 4.354

5.  Catalytic C(sp3)-H Alkylation via an Iron Carbene Intermediate.

Authors:  Jennifer R Griffin; Chloe I Wendell; Jacob A Garwin; M Christina White
Journal:  J Am Chem Soc       Date:  2017-09-22       Impact factor: 15.419

6.  C-H Insertion via Ruthenium Catalyzed gem-Hydrogenation of 1,3-Enynes.

Authors:  Sebastian Peil; Alejandro Gutiérrez González; Markus Leutzsch; Alois Fürstner
Journal:  J Am Chem Soc       Date:  2022-02-16       Impact factor: 15.419

7.  Stereoselective Radical C-H Alkylation with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis.

Authors:  Xin Cui; Xue Xu; Li-Mei Jin; Lukasz Wojtas; X Peter Zhang
Journal:  Chem Sci       Date:  2015-02       Impact factor: 9.825

Review 8.  Enantioselective carbenoid insertion into C(sp(3))-H bonds.

Authors:  J V Santiago; A H L Machado
Journal:  Beilstein J Org Chem       Date:  2016-05-04       Impact factor: 2.883
  8 in total

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