Literature DB >> 20030317

One-pot highly diastereoselective synthesis of cis-vinylaziridines via the sulfur ylide-mediated aziridination and palladium(0)-catalyzed isomerization.

Ben-Hu Zhu1, Jun-Cheng Zheng, Chang-Bin Yu, Xiu-Li Sun, Yong-Gui Zhou, Qi Shen, Yong Tang.   

Abstract

Highly diastereoselective synthesis of cis-trisubstituted vinylaziridines containing a quaternary carbon center is realized by a one-pot protocol in which the combination of sulfur ylide-mediated aziridination of cyclic ketimines and Pd(0)-catalyzed isomerization is employed successfully.

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Year:  2010        PMID: 20030317     DOI: 10.1021/ol9027072

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Protecting group-directed annulations of tetra-substituted oxindole olefins and sulfur ylides: regio- and chemoselective synthesis of cyclopropane- and dihydrofuran-fused spirooxindoles.

Authors:  Jing-Wen Kang; Xiang Li; Fei-Yu Chen; Yuan Luo; Shu-Cang Zhang; Bin Kang; Cheng Peng; Xu Tian; Bo Han
Journal:  RSC Adv       Date:  2019-04-17       Impact factor: 4.036

2.  Construct indeno[1,2-b]oxepine or cis-cyclopropylacrylate by sulfur ylides.

Authors:  Qinfang Chen; Yihao Pan; Dongxin Zhao; Weiran Yang; Jing Zheng
Journal:  RSC Adv       Date:  2020-06-08       Impact factor: 3.361

  2 in total

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