| Literature DB >> 20024333 |
Barry C Pemberton1, Nilotpal Barooah, D K Srivatsava, J Sivaguru.
Abstract
Cucurbit[8]uril (as low as 10 mol%) acts as a supramolecular catalytic nanoreaction vessel and facilitates the photodimerization of coumarins in water leading to syn dimers. Saturation kinetics shows a sigmoidal dependence with a turnover number of 3.4 min(-1) and a Hill constant of 1.8 indicating a co-operative mechanism in the catalytic process.Entities:
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Year: 2009 PMID： 20024333 DOI： 10.1039/b920605a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222