| Literature DB >> 20024303 |
Ga Young Park1, Yunho Lee, Dong-Heon Lee, Julia S Woertink, Amy A Narducci Sarjeant, Edward I Solomon, Kenneth D Karlin.
Abstract
[(ANS)Cu(I)(CH(3)CN)](+) reacts with O(2) giving [{(ANS)Cu(II)}(2)(micro-eta(2):eta(2)-O(2)(2-))](2+), nu(O-O) = 731 cm(-1), shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a -S(Ph) group. The finding is a rare occurrence and new for side-on O(2)(2-) binding.Entities:
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Year: 2009 PMID: 20024303 PMCID: PMC2908150 DOI: 10.1039/b918616f
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222