Literature DB >> 20024303

Thioether S-ligation in a side-on micro-eta2:eta2-peroxodicopperii complex.

Ga Young Park1, Yunho Lee, Dong-Heon Lee, Julia S Woertink, Amy A Narducci Sarjeant, Edward I Solomon, Kenneth D Karlin.   

Abstract

[(ANS)Cu(I)(CH(3)CN)](+) reacts with O(2) giving [{(ANS)Cu(II)}(2)(micro-eta(2):eta(2)-O(2)(2-))](2+), nu(O-O) = 731 cm(-1), shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a -S(Ph) group. The finding is a rare occurrence and new for side-on O(2)(2-) binding.

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Year:  2009        PMID: 20024303      PMCID: PMC2908150          DOI: 10.1039/b918616f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  23 in total

Review 1.  Reactivity of dioxygen-copper systems.

Authors:  Elizabeth A Lewis; William B Tolman
Journal:  Chem Rev       Date:  2004-02       Impact factor: 60.622

2.  Resonance raman investigation of equatorial ligand donor effects on the Cu(2)O(2)(2+) core in end-on and side-on mu-peroxo-dicopper(II) and bis-mu-oxo-dicopper(III) complexes.

Authors:  Mark J Henson; Michael A Vance; Christiana Xin Zhang; Hong-Chang Liang; Kenneth D Karlin; Edward I Solomon
Journal:  J Am Chem Soc       Date:  2003-04-30       Impact factor: 15.419

3.  Tripodal bis(imidazole) thioether copper(I) complexes: mimics of the Cu(B) site of hydroxylase enzymes.

Authors:  L Zhou; D Powell; K M Nicholas
Journal:  Inorg Chem       Date:  2006-05-15       Impact factor: 5.165

4.  The catalytic mechanism of peptidylglycine alpha-hydroxylating monooxygenase investigated by computer simulation.

Authors:  Alejandro Crespo; Marcelo A Martí; Adrian E Roitberg; L Mario Amzel; Darío A Estrin
Journal:  J Am Chem Soc       Date:  2006-10-04       Impact factor: 15.419

5.  Contrasting copper-dioxygen chemistry arising from alike tridentate alkyltriamine copper(I) complexes.

Authors:  Hong-Chang Liang; Christiana Xin Zhang; Mark J Henson; Roger D Sommer; Karen R Hatwell; Susan Kaderli; Andreas D Zuberbühler; Arnold L Rheingold; Edward I Solomon; Kenneth D Karlin
Journal:  J Am Chem Soc       Date:  2002-04-24       Impact factor: 15.419

6.  Oxygen activation by the noncoupled binuclear copper site in peptidylglycine alpha-hydroxylating monooxygenase. Reaction mechanism and role of the noncoupled nature of the active site.

Authors:  Peng Chen; Edward I Solomon
Journal:  J Am Chem Soc       Date:  2004-04-21       Impact factor: 15.419

Review 7.  Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity.

Authors:  Lanying Q Hatcher; Kenneth D Karlin
Journal:  J Biol Inorg Chem       Date:  2004-08-10       Impact factor: 3.358

8.  Dioxygen binds end-on to mononuclear copper in a precatalytic enzyme complex.

Authors:  Sean T Prigge; Betty A Eipper; Richard E Mains; L Mario Amzel
Journal:  Science       Date:  2004-05-07       Impact factor: 47.728

9.  Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues.

Authors:  Dong-Heon Lee; Lanying Q Hatcher; Michael A Vance; Ritimukta Sarangi; Ashley E Milligan; Amy A Narducci Sarjeant; Christopher D Incarvito; Arnold L Rheingold; Keith O Hodgson; Britt Hedman; Edward I Solomon; Kenneth D Karlin
Journal:  Inorg Chem       Date:  2007-06-20       Impact factor: 5.165

10.  Effects of thioether substituents on the O2 reactivity of beta-diketiminate-Cu(I) complexes: probing the role of the methionine ligand in copper monooxygenases.

Authors:  Nermeen W Aboelella; Benjamin F Gherman; Lyndal M R Hill; John T York; Nicole Holm; Victor G Young; Christopher J Cramer; William B Tolman
Journal:  J Am Chem Soc       Date:  2006-03-15       Impact factor: 15.419

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  8 in total

1.  Sulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species.

Authors:  Yunho Lee; Dong-Heon Lee; Ga Young Park; Heather R Lucas; Amy A Narducci Sarjeant; Matthew T Kieber-Emmons; Michael A Vance; Ashley E Milligan; Edward I Solomon; Kenneth D Karlin
Journal:  Inorg Chem       Date:  2010-10-04       Impact factor: 5.165

Review 2.  Activation of dioxygen by copper metalloproteins and insights from model complexes.

Authors:  David A Quist; Daniel E Diaz; Jeffrey J Liu; Kenneth D Karlin
Journal:  J Biol Inorg Chem       Date:  2016-12-05       Impact factor: 3.358

Review 3.  Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.

Authors:  Courtney E Elwell; Nicole L Gagnon; Benjamin D Neisen; Debanjan Dhar; Andrew D Spaeth; Gereon M Yee; William B Tolman
Journal:  Chem Rev       Date:  2017-01-19       Impact factor: 60.622

4.  Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms.

Authors:  Jeffrey J Liu; Daniel E Diaz; David A Quist; Kenneth D Karlin
Journal:  Isr J Chem       Date:  2016-07-26       Impact factor: 3.333

5.  A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity.

Authors:  Sunghee Kim; Jung Yoon Lee; Ryan E Cowley; Jake W Ginsbach; Maxime A Siegler; Edward I Solomon; Kenneth D Karlin
Journal:  J Am Chem Soc       Date:  2015-02-20       Impact factor: 15.419

Review 6.  Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function.

Authors:  Suzanne M Adam; Gayan B Wijeratne; Patrick J Rogler; Daniel E Diaz; David A Quist; Jeffrey J Liu; Kenneth D Karlin
Journal:  Chem Rev       Date:  2018-10-29       Impact factor: 60.622

7.  Tuning of the copper-thioether bond in tetradentate N₃S(thioether) ligands; O-O bond reductive cleavage via a [Cu(II)₂(μ-1,2-peroxo)]²⁺/[Cu(III)₂(μ-oxo)₂]²⁺ equilibrium.

Authors:  Sunghee Kim; Jake W Ginsbach; A Imtiaz Billah; Maxime A Siegler; Cathy D Moore; Edward I Solomon; Kenneth D Karlin
Journal:  J Am Chem Soc       Date:  2014-05-22       Impact factor: 15.419

8.  A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity.

Authors:  Mayukh Bhadra; Wesley J Transue; Hyeongtaek Lim; Ryan E Cowley; Jung Yoon C Lee; Maxime A Siegler; Patrick Josephs; Gerald Henkel; Markus Lerch; Siegfried Schindler; Adam Neuba; Keith O Hodgson; Britt Hedman; Edward I Solomon; Kenneth D Karlin
Journal:  J Am Chem Soc       Date:  2021-03-08       Impact factor: 15.419

  8 in total

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