Literature DB >> 20024281

Synthesis of transition metal isocyanide compounds from carbonyl complexes via reaction with Li[Me3SiNR].

Wesley Sattler1, Gerard Parkin.   

Abstract

The reaction between a transition metal carbonyl compound, L(n)MCO, and Li[Me(3)SiNR] yields the corresponding isocyanide derivative, L(n)MCNR, thereby providing a new route to transition metal isocyanide compounds that does not require the use of free isocyanides as reagents.

Entities:  

Year:  2009        PMID： 20024281     DOI： 10.1039/b917156h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Tuning π-Acceptor/σ-Donor Ratio of the 2-Isocyanoazulene Ligand: Non-Fluorinated Rival of Pentafluorophenyl Isocyanide and Trifluorovinyl Isocyanide Discovered.

Authors:  Mason D Hart; John J Meyers; Zachary A Wood; Toshinori Nakakita; Jason C Applegate; Nathan R Erickson; Nikolay N Gerasimchuk; Mikhail V Barybin
Journal:  Molecules       Date:  2021-02-12       Impact factor: 4.411

2.  First π-linker featuring mercapto and isocyano anchoring groups within the same molecule: Synthesis, heterobimetallic complexation and self-assembly on Au(111).

Authors:  Jason C Applegate; Monisola K Okeowo; Nathan R Erickson; Brad M Neal; Cindy L Berrie; Nikolay N Gerasimchukand; Mikhail V Barybin
Journal:  Chem Sci       Date:  2015-11-20       Impact factor: 9.825
  2 in total

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