Literature DB >> 20000671

Palladium-catalyzed decarboxylative benzylation of diphenylglycinate imines.

Wendy H Fields1, Jason J Chruma.   

Abstract

General reaction conditions for the Pd-catalyzed decarboxylative benzylation of benzyl diphenylglycinate imines are described. The overall procedure requires a simple catalyst/ligand combination to form a new Csp(3)-Csp(3) bond. Microwave irradiation greatly accelerated the transformation. Moreover, various heteroaromatic moieties are tolerated in both the imine and ester components.

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Year:  2010        PMID： 20000671     DOI： 10.1021/ol902651j

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  18 in total

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2.  Deacylative allylation: allylic alkylation via retro-Claisen activation.

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3.  Umpolung Synthesis of Diarylmethylamines via Palladium-Catalyzed Arylation of N-Benzyl Aldimines.

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Journal:  Adv Synth Catal       Date:  2016-05-12       Impact factor: 5.837

Review 4.  Transition metal-catalyzed decarboxylative allylation and benzylation reactions.

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Journal:  Chem Rev       Date:  2011-01-14       Impact factor: 60.622

5.  Palladium-catalyzed C3-benzylation of indoles.

Authors:  Ye Zhu; Viresh H Rawal
Journal:  J Am Chem Soc       Date:  2011-12-09       Impact factor: 15.419

6.  Palladium-catalyzed C(sp(3))-H Arylation of N-Boc benzylalkylamines via a deprotonative cross-coupling process.

Authors:  Nusrah Hussain; Byeong-Seon Kim; Patrick J Walsh
Journal:  Chemistry       Date:  2015-06-30       Impact factor: 5.236

7.  Decarboxylative benzylations of alkynes and ketones.

Authors:  Robert R P Torregrosa; Yamuna Ariyarathna; Kalicharan Chattopadhyay; Jon A Tunge
Journal:  J Am Chem Soc       Date:  2010-07-14       Impact factor: 15.419

8.  Transition-metal-free chemo- and regioselective vinylation of azaallyls.

Authors:  Minyan Li; Osvaldo Gutierrez; Simon Berritt; Ana Pascual-Escudero; Ahmet Yeşilçimen; Xiaodong Yang; Javier Adrio; Georgia Huang; Eiko Nakamaru-Ogiso; Marisa C Kozlowski; Patrick J Walsh
Journal:  Nat Chem       Date:  2017-04-17       Impact factor: 24.427

9.  Palladium-catalyzed, pyrrolidine-mediated arylmethylation of ketones and aldehydes with coumarinyl(methyl) acetates.

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Journal:  Org Biomol Chem       Date:  2012-07-25       Impact factor: 3.876

10.  Preparation and Applications of 4-Methoxybenzyl Esters in Organic Synthesis.

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Journal:  Org Prep Proced Int       Date:  2016-01-29       Impact factor: 1.628
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