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Literature DB >> 20000348

Palladium-catalyzed alkoxylation of N-methoxybenzamides via direct sp2 C-H bond activation.

Abstract

The palladium-catalyzed ortho-alkoxylation of N-methoxybenzamides has been demonstrated. With the CONHOMe group as a directing group, the aromatic C-H bond can be functionalized efficiently to generate ortho-alkoxylated derivatives in moderate to good yields.

Entities: Chemical

Year: 2010 PMID： 20000348 DOI： 10.1021/jo902139b

Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354

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Cited

10 in total

Review 1. A Simple and Versatile Amide Directing Group for C-H Functionalizations.

Authors: Ru-Yi Zhu; Marcus E Farmer; Yan-Qiao Chen; Jin-Quan Yu
Journal: Angew Chem Int Ed Engl Date: 2016-08-01 Impact factor: 15.336

2. Bimetallic reductive elimination from dinuclear Pd(III) complexes.

Authors: David C Powers; Diego Benitez; Ekaterina Tkatchouk; William A Goddard; Tobias Ritter
Journal: J Am Chem Soc Date: 2010-10-13 Impact factor: 15.419

3. Synthesis of catechols from phenols via Pd-catalyzed silanol-directed C-H oxygenation.

Authors: Chunhui Huang; Nugzar Ghavtadze; Buddhadeb Chattopadhyay; Vladimir Gevorgyan
Journal: J Am Chem Soc Date: 2011-10-18 Impact factor: 15.419

4. Total Synthesis of (-)-Kopsifoline A and (+)-Kopsifoline E.

Authors: In-Soo Myeong; Nadide Hazal Avci; Mohammad Movassaghi
Journal: Org Lett Date: 2021-11-12 Impact factor: 6.072

5. Pd(II)-catalyzed C-H functionalizations directed by distal weakly coordinating functional groups.

Authors: Gang Li; Li Wan; Guofu Zhang; Dasheng Leow; Jillian Spangler; Jin-Quan Yu
Journal: J Am Chem Soc Date: 2015-03-24 Impact factor: 15.419

6. Concise Total Syntheses of (+)-Haplocidine and (+)-Haplocine via Late-Stage Oxidation of (+)-Fendleridine Derivatives.

Authors: Kolby L White; Mohammad Movassaghi
Journal: J Am Chem Soc Date: 2016-08-26 Impact factor: 15.419

Palladium-catalyzed alkoxylation of N-methoxybenzamides via direct sp2 C-H bond activation.

Review 1. A Simple and Versatile Amide Directing Group for C-H Functionalizations.

2. Bimetallic reductive elimination from dinuclear Pd(III) complexes.

3. Synthesis of catechols from phenols via Pd-catalyzed silanol-directed C-H oxygenation.

4. Total Synthesis of (-)-Kopsifoline A and (+)-Kopsifoline E.

5. Pd(II)-catalyzed C-H functionalizations directed by distal weakly coordinating functional groups.

6. Concise Total Syntheses of (+)-Haplocidine and (+)-Haplocine via Late-Stage Oxidation of (+)-Fendleridine Derivatives.

Review 7. Cross-dehydrogenative coupling for the intermolecular C-O bond formation.

8. Palladium(II)-catalyzed enantioselective C(sp³)-H activation using a chiral hydroxamic acid ligand.

9. Cobalt-catalyzed peri-selective alkoxylation of 1-naphthylamine derivatives.

10. Late-Stage C-H Acylation of Tyrosine-Containing Oligopeptides with Alcohols.