| Literature DB >> 20000335 |
Abstract
The biomimetic total synthesis of penifulvins B and C uses a meta-photocycloaddition as a key step which gives rapid access to the fenestrane-type carboskeleton with control of an onring quaternary stereocenter. The route is concise, stereocontrolled, scaleable, and flexibile and requires only one protecting group.Entities:
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Year: 2010 PMID: 20000335 DOI: 10.1021/ol902594b
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005