Literature DB >> 19919154

An olefination via ruthenium-catalyzed decarbonylative addition of aldehydes to terminal alkynes.

Xiangyu Guo1, Jun Wang, Chao-Jun Li.   

Abstract

A ruthenium-catalyzed olefination via decarbonylative addition of aldehydes and alkynes has been developed. A strong electronic effect and high chemoselectivity between aromatic and aliphatic aldehydes were observed in this reaction.

Entities:  

Year:  2009        PMID： 19919154     DOI： 10.1021/ja906265a

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  8 in total

1.  Intermolecular Dehydrative Coupling Reaction of Arylketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: A Novel Ketone Olefination Method via Vinyl C-H Bond Activation.

Authors:  Chae S Yi; Do W Lee
Journal:  Organometallics       Date:  2010-03-19       Impact factor: 3.876

2.  Synthesis of Alkyl Halides from Aldehydes via Deformylative Halogenation.

Authors:  Shengzong Liang; Tatsuya Kumon; Ricardo A Angnes; Melissa Sanchez; Bo Xu; Gerald B Hammond
Journal:  Org Lett       Date:  2019-05-03       Impact factor: 6.005

3.  Intermolecular oxidative decarbonylative [2 + 2 + 2] carbocyclization of N-(2-ethynylaryl)acrylamides with tertiary and secondary alkyl aldehydes involving C(sp3)-H functionalization.

Authors:  Yang Li; Gao-Hui Pan; Ming Hu; Bang Liu; Ren-Jie Song; Jin-Heng Li
Journal:  Chem Sci       Date:  2016-07-21       Impact factor: 9.825

4.  Ruthenium(ii)-catalyzed olefination via carbonyl reductive cross-coupling.

Authors:  Wei Wei; Xi-Jie Dai; Haining Wang; Chenchen Li; Xiaobo Yang; Chao-Jun Li
Journal:  Chem Sci       Date:  2017-10-09       Impact factor: 9.825

5.  Nickel-catalyzed Suzuki-Miyaura cross-couplings of aldehydes.

Authors:  Lin Guo; Watchara Srimontree; Chen Zhu; Bholanath Maity; Xiangqian Liu; Luigi Cavallo; Magnus Rueping
Journal:  Nat Commun       Date:  2019-04-29       Impact factor: 14.919

6.  Visible-light-induced transition metal and photosensitizer free decarbonylative addition of amino-arylaldehydes to ketones.

Authors:  Yi Wang; Yatao Lang; Chao-Jun Li; Huiying Zeng
Journal:  Chem Sci       Date:  2021-12-21       Impact factor: 9.825

7.  Nickel-Catalyzed Stereoselective Alkenylation of Ketones Mediated by Hydrazine.

Authors:  Shumei Xia; Dawei Cao; Huiying Zeng; Liang-Nian He; Chao-Jun Li
Journal:  JACS Au       Date:  2022-07-25

8.  Fe-catalyzed Decarbonylative Alkylative Spirocyclization of N-Arylcinnamamides: Access to Alkylated 1-Azaspirocyclohexadienones.

Authors:  Xiang Peng; Ren-Xiang Liu; Xiang-Yan Xiao; Luo Yang
Journal:  Molecules       Date:  2020-01-21       Impact factor: 4.411
  8 in total

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