Literature DB >> 19905783

Ferroelectricity in ultrathin BaTiO3 films: probing the size effect by ultraviolet Raman spectroscopy.

D A Tenne1, P Turner, J D Schmidt, M Biegalski, Y L Li, L Q Chen, A Soukiassian, S Trolier-McKinstry, D G Schlom, X X Xi, D D Fong, P H Fuoss, J A Eastman, G B Stephenson, C Thompson, S K Streiffer.   

Abstract

We demonstrate the dramatic effect of film thickness on the ferroelectric phase transition temperature Tc in strained BaTiO3 films grown on SrTiO3 substrates. Using variable-temperature ultraviolet Raman spectroscopy enables measuring Tc in films as thin as 1.6 nm, and a film thickness variation from 1.6 to 10 nm leads to Tc tuning from 70 to about 925 K. Raman data are consistent with synchrotron x-ray scattering results, which indicate the presence of 180 degrees domains below Tc, and thermodynamic phase-field model calculations of Tc as a function of thickness.

Entities:  

Year:  2009        PMID: 19905783     DOI: 10.1103/PhysRevLett.103.177601

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


  7 in total

1.  Switching of ferroelectric polarization in epitaxial BaTiO₃ films on silicon without a conducting bottom electrode.

Authors:  Catherine Dubourdieu; John Bruley; Thomas M Arruda; Agham Posadas; Jean Jordan-Sweet; Martin M Frank; Eduard Cartier; David J Frank; Sergei V Kalinin; Alexander A Demkov; Vijay Narayanan
Journal:  Nat Nanotechnol       Date:  2013-09-29       Impact factor: 39.213

2.  Nanoscale design of polarization in ultrathin ferroelectric heterostructures.

Authors:  Gabriele De Luca; Nives Strkalj; Sebastian Manz; Corinne Bouillet; Manfred Fiebig; Morgan Trassin
Journal:  Nat Commun       Date:  2017-11-10       Impact factor: 14.919

3.  Possible absence of critical thickness and size effect in ultrathin perovskite ferroelectric films.

Authors:  Peng Gao; Zhangyuan Zhang; Mingqiang Li; Ryo Ishikawa; Bin Feng; Heng-Jui Liu; Yen-Lin Huang; Naoya Shibata; Xiumei Ma; Shulin Chen; Jingmin Zhang; Kaihui Liu; En-Ge Wang; Dapeng Yu; Lei Liao; Ying-Hao Chu; Yuichi Ikuhara
Journal:  Nat Commun       Date:  2017-06-06       Impact factor: 14.919

4.  Direct observation of room-temperature out-of-plane ferroelectricity and tunneling electroresistance at the two-dimensional limit.

Authors:  H Wang; Z R Liu; H Y Yoong; T R Paudel; J X Xiao; R Guo; W N Lin; P Yang; J Wang; G M Chow; T Venkatesan; E Y Tsymbal; H Tian; J S Chen
Journal:  Nat Commun       Date:  2018-08-20       Impact factor: 14.919

5.  Functional ferroelectric tunnel junctions on silicon.

Authors:  Rui Guo; Zhe Wang; Shengwei Zeng; Kun Han; Lisen Huang; Darrell G Schlom; T Venkatesan; Jingsheng Chen
Journal:  Sci Rep       Date:  2015-07-28       Impact factor: 4.379

6.  Ferroelectricity and Self-Polarization in Ultrathin Relaxor Ferroelectric Films.

Authors:  Peixian Miao; Yonggang Zhao; Nengneng Luo; Diyang Zhao; Aitian Chen; Zhong Sun; Meiqi Guo; Meihong Zhu; Huiyun Zhang; Qiang Li
Journal:  Sci Rep       Date:  2016-01-28       Impact factor: 4.379

7.  In situ X-ray diffraction and the evolution of polarization during the growth of ferroelectric superlattices.

Authors:  Benjamin Bein; Hsiang-Chun Hsing; Sara J Callori; John Sinsheimer; Priya V Chinta; Randall L Headrick; Matthew Dawber
Journal:  Nat Commun       Date:  2015-12-04       Impact factor: 14.919

  7 in total

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