| Literature DB >> 19885513 |
Mark R Crimmin1, Anthony G M Barrett, Michael S Hill, Dugald J MacDougall, Mary F Mahon, Panayiotis A Procopiou.
Abstract
Well defined dialkyls of the heavier alkaline earth elements, [M{CH(SiMe(3))(2)}(2)(THF)(n)] [M = Ca, n = 2; M = Sr, n = 3; M = Ba, n = 3] react to form either the heteroleptic beta-diketiminato alkyl when M = Ca or unusual 'C-H activation' products in which a methyl group of the ligand is deprotonated when M = Sr or Ba.Entities:
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Year: 2009 PMID： 19885513 DOI： 10.1039/b917466b
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390