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Literature DB >> 19885484

Synthesis and structure of "16-electron" rhodium(III) catalysts fortransfer hydrogenation of a cyclic imine: mechanistic implications.

A John Blacker¹, Eric Clot, Simon B Duckett, Odile Eisenstein, Jake Grace, Ainara Nova, Robin N Perutz, David J Taylor, Adrian C Whitwood.

Abstract

Significant Rh-NH p-bonding in formally 16-electron(eta5-C5Me5)Rh(XNC6H4NX') (X, X' = H or Ts) is shownby structural features and by DFT calculations;(eta5-C5Me5)Rh(TsNC6H4NH) is the fastest transfer hydrogenationcatalyst of the three complexes and generates a formate complexunder catalytic conditions.

Entities: Chemical

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Year: 2009 PMID： 19885484 DOI： 10.1039/b912943j

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

3 in total

1. Proton-hydride tautomerism in hydrogen evolution catalysis.

Authors: Luis M Aguirre Quintana; Samantha I Johnson; Sydney L Corona; Walther Villatoro; William A Goddard; Michael K Takase; David G VanderVelde; Jay R Winkler; Harry B Gray; James D Blakemore
Journal: Proc Natl Acad Sci U S A Date: 2016-05-24 Impact factor: 11.205

2. Tuning Pt^II -Based Donor-Acceptor Systems through Ligand Design: Effects on Frontier Orbitals, Redox Potentials, UV/Vis/NIR Absorptions, Electrochromism, and Photocatalysis.

Authors: Sebastian Sobottka; Maite Nößler; Andrew L Ostericher; Gunter Hermann; Noah Z Subat; Julia Beerhues; Margarethe Behr-van der Meer; Lisa Suntrup; Uta Albold; Stephan Hohloch; Jean Christophe Tremblay; Biprajit Sarkar
Journal: Chemistry Date: 2020-01-22 Impact factor: 5.236

3. Base-Promoted, Remote C-H Activation at a Cationic (η⁵-C₅Me₅)Ir(III) Center Involving Reversible C-C Bond Formation of Bound C₅Me₅.

Authors: Juan J Moreno; María F Espada; Jesús Campos; Joaquín López-Serrano; Stuart A Macgregor; Ernesto Carmona
Journal: J Am Chem Soc Date: 2019-02-05 Impact factor: 15.419

3 in total

Synthesis and structure of "16-electron" rhodium(III) catalysts fortransfer hydrogenation of a cyclic imine: mechanistic implications.

1. Proton-hydride tautomerism in hydrogen evolution catalysis.

2. Tuning PtII -Based Donor-Acceptor Systems through Ligand Design: Effects on Frontier Orbitals, Redox Potentials, UV/Vis/NIR Absorptions, Electrochromism, and Photocatalysis.

3. Base-Promoted, Remote C-H Activation at a Cationic (η5-C5Me5)Ir(III) Center Involving Reversible C-C Bond Formation of Bound C5Me5.

2. Tuning Pt^II -Based Donor-Acceptor Systems through Ligand Design: Effects on Frontier Orbitals, Redox Potentials, UV/Vis/NIR Absorptions, Electrochromism, and Photocatalysis.

3. Base-Promoted, Remote C-H Activation at a Cationic (η⁵-C₅Me₅)Ir(III) Center Involving Reversible C-C Bond Formation of Bound C₅Me₅.