| Literature DB >> 19865675 |
Henrike Bladt1, Silvia Gonzalez Calera, Jonathan M Goodman, Robert J Less, Vesal Naseri, Alexander Steiner, Dominic S Wright.
Abstract
The photochemical dyotropic (two-bond shift) rearrangement of the phosphazane cage alpha-[PN(t)Bu](4) (alpha) into the isomer beta-[PN(t)Bu](4) (beta) occurs via a multi-step radical mechanism; the structures of the alpha and beta isomers are directly analogous to isovalent alpha- and beta-As(4)S(4) and P(4)S(4).Entities:
Year: 2009 PMID： 19865675 DOI： 10.1039/b914370j
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222