| Literature DB >> 19859589 |
Natalya V Izarova1, Rosa Ngo Biboum, Bineta Keita, Maria Mifsud, Isabel W C E Arends, Geoffrey B Jameson, Ulrich Kortz.
Abstract
A novel heteropolyoxopalladate structural type has been discovered: the polyoxo-15-palladate(II) [Pd(0.4)Na(0.6) subsetPd(15)P(10)O(50)H(6.6)](12-) (Pd(15)) has been prepared in a one-pot self-assembly reaction and characterized by single-crystal XRD, elemental analysis, IR, TGA, (31)P NMR and electrochemistry; preliminary catalytic studies showed that Pd(15) is active as a catalyst in alcohol oxidation by dioxygen.Entities:
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Year: 2009 PMID: 19859589 DOI: 10.1039/b917079k
Source DB: PubMed Journal: Dalton Trans ISSN: 1477-9226 Impact factor: 4.390