Literature DB >> 19847352

Gold and platinum catalysis--a convenient tool for generating molecular complexity.

Alois Fürstner1.   

Abstract

This critical review intends to familiarize the reader with the essence of pi-acid catalysis, in particular with reactions or reaction cascades effected by gold and platinum complexes. Even though materialized in apparently different reactivity modes, such noble metal catalyzed processes can be easily rationalized on the basis of a uniform mechanistic scheme that is outlined in detail. The resulting increase in molecular complexity is illustrated by selected natural product total syntheses and the formation of various intricate non-natural compounds (106 references).

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Year:  2009        PMID： 19847352     DOI： 10.1039/b816696j

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN： 0306-0012            Impact factor:   54.564


  106 in total

1.  Total synthesis: towards artificial terpene cyclases.

Authors:  Matthieu Willot; Mathias Christmann
Journal:  Nat Chem       Date:  2010-07       Impact factor: 24.427

2.  C-C coupling reactivity of an alkylgold(III) fluoride complex with arylboronic acids.

Authors:  Neal P Mankad; F Dean Toste
Journal:  J Am Chem Soc       Date:  2010-09-22       Impact factor: 15.419

3.  Triazole-gold (TAAu) catalyzed three-component coupling (A3 reaction) towards the synthesis of 2, 4-disubstituted quinoline derivatives.

Authors:  Fusong Zhang; Qi Lai; Xiaodong Shi; Zhiguang Song
Journal:  Chin Chem Lett       Date:  2018-05-24       Impact factor: 6.779

4.  Gold(I)-catalyzed enantioselective [3+2] and [3+3] cycloaddition reactions of propargyl acetals/ketals.

Authors:  Cristina Navarro; Nathan D Shapiro; Maurizio Bernasconi; Takahiro Horibe; F Dean Toste
Journal:  Tetrahedron       Date:  2015-09-02       Impact factor: 2.457

5.  Strong electronic and counterion effects on geminal digold formation and reactivity as revealed by gold(I)-aryl model complexes.

Authors:  Dieter Weber; T David Jones; Laura L Adduci; Michel R Gagné
Journal:  Angew Chem Int Ed Engl       Date:  2012-01-25       Impact factor: 15.336

6.  Investigations on Gold-Catalyzed Thioalkyne Activation Toward Facile Synthesis of Ketene Dithioacetals.

Authors:  Xiaohan Ye; Jin Wang; Shengtao Ding; Seyedmorteza Hosseyni; Lukasz Wojtas; Novruz G Akhmedov; Xiaodong Shi
Journal:  Chemistry       Date:  2017-07-20       Impact factor: 5.236

7.  Chiral Brønsted acid from a cationic gold(I) complex: catalytic enantioselective protonation of silyl enol ethers of ketones.

Authors:  Cheol Hong Cheon; Osamu Kanno; F Dean Toste
Journal:  J Am Chem Soc       Date:  2011-08-04       Impact factor: 15.419

8.  Mechanistic Studies of Gold and Palladium Cooperative Dual-Catalytic Cross-Coupling Systems.

Authors:  Mohammad Al-Amin; Katrina E Roth; Suzanne A Blum
Journal:  ACS Catal       Date:  2014-02-07       Impact factor: 13.084

9.  Rhodium-catalyzed intra- and intermolecular [5 + 2] cycloaddition of 3-acyloxy-1,4-enyne and alkyne with concomitant 1,2-acyloxy migration.

Authors:  Xing-Zhong Shu; Xiaoxun Li; Dongxu Shu; Suyu Huang; Casi M Schienebeck; Xin Zhou; Patrick J Robichaux; Weiping Tang
Journal:  J Am Chem Soc       Date:  2012-03-12       Impact factor: 15.419

10.  Accessing alternative reaction pathways of the intermolecular condensation between homo-propargyl alcohols and terminal alkynes through divergent gold catalysis.

Authors:  Courtney A Smith; Stephen E Motika; Lukasz Wojtas; Xiaodong Shi
Journal:  Chem Commun (Camb)       Date:  2017-02-16       Impact factor: 6.222
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