N-P transition sensing behaviors of ZnO nanotubes exposed to NO2 gas.

Hydrothermally synthesized ZnO nanotube arrays were used to fabricate the gas sensor for detection of the toxic gas NO2. The ZnO nanotube gas sensor exhibited sensitive response to NO2 down to 500 ppb at low temperature 30 degrees C. Abnormal temperature-dependent and concentration-dependent N-P transition behaviors were observed. The excellent sensing ability of the sensor and their anomalous conductivity behaviors may be attributed to the unique surface conductivity related to the hollow nanostructure feature. These sensing behaviors may help to comprehensively understand the sensing mechanism of 1D ZnO nanostructures and improve the selectivity of the ZnO gas sensor.