Literature DB >> 19842662

Extremely efficient alkane oxidation by a new catalytic reagent H(2)O(2)/Os(3)(CO)(12)/pyridine.

Georgiy B Shul'pin1, Yuriy N Kozlov, Lidia S Shul'pina, Alexander R Kudinov, Dalmo Mandelli.   

Abstract

Triosmium dodecacarbonyl catalyzes a very efficient oxidation of alkanes by H(2)O(2) in MeCN to afford alkyl hydroperoxides (primary products) as well as alcohols and ketones (aldehydes) at 60 degrees C if pyridine is added in a low concentration. Turnover numbers attain 60,000, and turnover frequencies are up to 24,000 h(-1).

Entities:  

Year:  2009        PMID： 19842662     DOI： 10.1021/ic901576r

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  5 in total

1.  Novel H-Bonded Synthons in Copper Supramolecular Frameworks with Aminoethylpiperazine-Based Ligands. Synthesis, Structure and Catalytic Activity.

Authors:  Oksana V Nesterova; Armando J L Pombeiro; Dmytro S Nesterov
Journal:  Materials (Basel)       Date:  2020-11-29       Impact factor: 3.623

2.  Oxido- and Dioxido-Vanadium(V) Complexes Supported on Carbon Materials: Reusable Catalysts for the Oxidation of Cyclohexane.

Authors:  Manas Sutradhar; Marta A Andrade; Sónia A C Carabineiro; Luísa M D R S Martins; Maria de Fátima C Guedes da Silva; Armando J L Pombeiro
Journal:  Nanomaterials (Basel)       Date:  2021-05-31       Impact factor: 5.076

3.  Greener Selective Cycloalkane Oxidations with Hydrogen Peroxide Catalyzed by Copper-5-(4-pyridyl)tetrazolate Metal-Organic Frameworks.

Authors:  Luísa Martins; Rajendar Nasani; Manideepa Saha; Shaikh Mobin; Suman Mukhopadhyay; Armando Pombeiro
Journal:  Molecules       Date:  2015-10-21       Impact factor: 4.411

4.  Peroxidative Oxidation of Alkanes and Alcohols under Mild Conditions by Di- and Tetranuclear Copper (II) Complexes of Bis (2-Hydroxybenzylidene) Isophthalohydrazide.

Authors:  Manas Sutradhar; Elisabete C B A Alegria; M Fátima C Guedes da Silva; Cai-Ming Liu; Armando J L Pombeiro
Journal:  Molecules       Date:  2018-10-19       Impact factor: 4.411

5.  Halide Control of N,N-Coordination versus N,C-Cyclometalation and Stereospecific Phenyl Ring Deuteration of Osmium(II) p-Cymene Phenylazobenzothiazole Complexes.

Authors:  Russell J Needham; Abraha Habtemariam; Nicolas P E Barry; Guy Clarkson; Peter J Sadler
Journal:  Organometallics       Date:  2017-11-09       Impact factor: 3.876
  5 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.