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Literature DB >> 19841818

Sp-sp(3) C-C bond formation via Fe(OTf)(3)/TfOH cocatalyzed coupling reaction of terminal alkynes with benzylic alcohols.

Abstract

An Fe(OTf)(3)/TfOH cocatalyzed sp-sp(3) C-C bond formation through the coupling of benzylic alcohols with terminal alkynes in the absence of base has been developed. H(2)O is the sole by-product.

Entities: Chemical

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Year: 2009 PMID： 19841818 DOI： 10.1039/b911905a

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

2 in total

1. New chiral phosphoramidite complexes of iron as catalytic precursors in the oxidation of activated methylene groups.

Authors: Pushkar Shejwalkar; Nigam P Rath; Eike B Bauer
Journal: Molecules Date: 2010-04-12 Impact factor: 4.411

2. Site-Selective C_sp³-C_sp/C_sp³-C_sp² Cross-Coupling Reactions Using Frustrated Lewis Pairs.

Authors: Ayan Dasgupta; Katarina Stefkova; Rasool Babaahmadi; Brian F Yates; Niklaas J Buurma; Alireza Ariafard; Emma Richards; Rebecca L Melen
Journal: J Am Chem Soc Date: 2021-03-15 Impact factor: 15.419

2 in total

Sp-sp(3) C-C bond formation via Fe(OTf)(3)/TfOH cocatalyzed coupling reaction of terminal alkynes with benzylic alcohols.

1. New chiral phosphoramidite complexes of iron as catalytic precursors in the oxidation of activated methylene groups.

2. Site-Selective Csp3-Csp/Csp3-Csp2 Cross-Coupling Reactions Using Frustrated Lewis Pairs.

2. Site-Selective C_sp³-C_sp/C_sp³-C_sp² Cross-Coupling Reactions Using Frustrated Lewis Pairs.