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Literature DB >> 19841800

Copper-catalyzed arene C-H bond cross-coupling.

Abstract

A highly regioselective, one-pot sequential iodination-copper-catalyzed cross-coupling of arene C-H bonds has been developed affording an efficient method for biaryl synthesis.

Entities: Chemical Disease Gene

Mesh：

Substances：
Carbon
Copper

Year: 2009 PMID： 19841800 PMCID： PMC2828042 DOI： 10.1039/b912890e

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

21 in total

1. Aryl-aryl bond formation one century after the discovery of the Ullmann reaction.

Authors: Jwanro Hassan; Marc Sévignon; Christel Gozzi; Emmanuelle Schulz; Marc Lemaire
Journal: Chem Rev Date: 2002-05 Impact factor: 60.622

2. An efficient bimetallic rhodium catalyst for the direct arylation of unactivated arenes.

Authors: Sebastian Proch; Rhett Kempe
Journal: Angew Chem Int Ed Engl Date: 2007 Impact factor: 15.336

3. FeCl2-catalyzed selective C--C bond formation by oxidative activation of a benzylic C--H bond.

Authors: Zhiping Li; Lin Cao; Chao-Jun Li
Journal: Angew Chem Int Ed Engl Date: 2007 Impact factor: 15.336

4. Efficient oxidative alkyne homocoupling catalyzed by a monomeric dicopper-substituted silicotungstate.

Authors: Keigo Kamata; Syuhei Yamaguchi; Miyuki Kotani; Kazuya Yamaguchi; Noritaka Mizuno
Journal: Angew Chem Int Ed Engl Date: 2008 Impact factor: 15.336

5. Direct ortho cupration: a new route to regioselectively functionalized aromatics.

Authors: Shinya Usui; Yuichi Hashimoto; James V Morey; Andrew E H Wheatley; Masanobu Uchiyama
Journal: J Am Chem Soc Date: 2007-11-16 Impact factor: 15.419

6. Twofold C-H functionalization: palladium-catalyzed ortho arylation of anilides.

Authors: Gordon Brasche; Jorge García-Fortanet; Stephen L Buchwald
Journal: Org Lett Date: 2008-05-09 Impact factor: 6.005

7. A copper-catalyzed, pH-neutral construction of high-enantiopurity peptidyl ketones from peptidic s-acylthiosalicylamides in air at room temperature.

Authors: Lanny S Liebeskind; Hao Yang; Hao Li
Journal: Angew Chem Int Ed Engl Date: 2009 Impact factor: 15.336

Copper-catalyzed arene C-H bond cross-coupling.

1. Aryl-aryl bond formation one century after the discovery of the Ullmann reaction.

2. An efficient bimetallic rhodium catalyst for the direct arylation of unactivated arenes.

3. FeCl2-catalyzed selective C--C bond formation by oxidative activation of a benzylic C--H bond.

4. Efficient oxidative alkyne homocoupling catalyzed by a monomeric dicopper-substituted silicotungstate.

5. Direct ortho cupration: a new route to regioselectively functionalized aromatics.

6. Twofold C-H functionalization: palladium-catalyzed ortho arylation of anilides.

7. A copper-catalyzed, pH-neutral construction of high-enantiopurity peptidyl ketones from peptidic s-acylthiosalicylamides in air at room temperature.

8. Application of Daugulis copper-catalyzed direct arylation to the synthesis of 5-aryl benzotriazepines.

9. Cu(II)-catalyzed direct and site-selective arylation of indoles under mild conditions.

10. Copper-catalyzed "click" reaction/direct arylation sequence: modular syntheses of 1,2,3-triazoles.

1. A general method for copper-catalyzed arene cross-dimerization.

2. Copper-catalyzed cyanation of heterocycle carbon-hydrogen bonds.

3. Ru-catalysed C-H arylation of indoles and pyrroles with boronic acids: scope and mechanistic studies.

4. Transition-Metal-Free Decarboxylative Iodination: New Routes for Decarboxylative Oxidative Cross-Couplings.