| Literature DB >> 19810766 |
Masafumi Ueda1, Hideto Miyabe, Takahiro Kimura, Eiko Kondoh, Takeaki Naito, Okiko Miyata.
Abstract
Intermolecular hydroxyalkylation of alpha,beta-unsaturated imines involving Et3B-mediated regioselective alkyl radical addition and subsequent hydroxylation with molecular oxygen has been developed, in which N-borylenamine generated by trapping of the enaminyl radical with Et3B was a key intermediate in the proposed aerobic hydroxylation mechanism.Entities:
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Year: 2009 PMID： 19810766 DOI： 10.1021/ol901912j
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005