Literature DB >> 19791774

Enantioselective total synthesis and determination of absolute configuration of vittatalactone.

Yvonne Schmidt1, Bernhard Breit.   

Abstract

The first asymmetric total synthesis of vittatalactone features the divergent synthesis of two diastereomers to assign the absolute configuration of the natural product. Its consecutive propionate and deoxypropionate stereogenic centers are established by enantioselective o-DPPB directed allylic substitution.

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Year:  2009        PMID： 19791774     DOI： 10.1021/ol901591t

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  β-Lactones: A Novel Class of Ca2+-Independent Phospholipase A2 (Group VIA iPLA2) Inhibitors with the Ability To Inhibit β-Cell Apoptosis.

Authors:  Christina Dedaki; Maroula G Kokotou; Varnavas D Mouchlis; Dimitris Limnios; Xiaoyong Lei; Carol T Mu; Sasanka Ramanadham; Victoria Magrioti; Edward A Dennis; George Kokotos
Journal:  J Med Chem       Date:  2019-03-12       Impact factor: 7.446

2.  Convergent synthesis of deoxypropionates.

Authors:  Peter S Diez; Glenn C Micalizio
Journal:  Angew Chem Int Ed Engl       Date:  2012-04-05       Impact factor: 15.336

3.  Asymmetric total synthesis of a putative sex pheromone component from the parasitoid wasp Trichogramma turkestanica.

Authors:  Danny Geerdink; Jeffrey Buter; Teris A van Beek; Adriaan J Minnaard
Journal:  Beilstein J Org Chem       Date:  2014-04-02       Impact factor: 2.883
  3 in total

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