| Literature DB >> 19787113 |
Natalie M Clark1, Pablo García-Alvarez, Alan R Kennedy, Charles T O'Hara, Gemma M Robertson.
Abstract
'Conventional' (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and 'unconventional' hydroxyl-incorporated sodium sodiate, [(-)-sparteine x Na(mu-HMDS)Na x (-)-sparteine](+)[Na(4)(mu-HMDS)(4)(OH)](-)--the complex anion of which is the first inverse crown ether anion.Entities:
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Year: 2009 PMID： 19787113 DOI： 10.1039/b908722b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222