Literature DB >> 19785406

Copolymerization of vinyl acetate with ethylene by palladium/alkylphosphine-sulfonate catalysts.

Shingo Ito1, Kagehiro Munakata, Akifumi Nakamura, Kyoko Nozaki.   

Abstract

Coordination copolymerization of vinyl acetate (VAc) with ethylene, leading to linear copolymers that possess in-chain -CH(2)CH(OAc)- units, has been accomplished using novel palladium complexes bearing alkylphosphine-sulfonate ligands.

Entities:  

Year:  2009        PMID: 19785406     DOI: 10.1021/ja9050839

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  4 in total

1.  Precision design of ethylene- and polar-monomer-based copolymers by organometallic-mediated radical polymerization.

Authors:  Anthony Kermagoret; Antoine Debuigne; Christine Jérôme; Christophe Detrembleur
Journal:  Nat Chem       Date:  2014-01-26       Impact factor: 24.427

2.  Irradiation-induced palladium-catalyzed decarboxylative desaturation enabled by a dual ligand system.

Authors:  Wan-Min Cheng; Rui Shang; Yao Fu
Journal:  Nat Commun       Date:  2018-12-06       Impact factor: 14.919

3.  Ultrahigh Branching of Main-Chain-Functionalized Polyethylenes by Inverted Insertion Selectivity.

Authors:  Yuxing Zhang; Chaoqun Wang; Stefan Mecking; Zhongbao Jian
Journal:  Angew Chem Int Ed Engl       Date:  2020-07-06       Impact factor: 15.336

4.  Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide-palladium catalysts.

Authors:  Yusuke Mitsushige; Brad P Carrow; Shingo Ito; Kyoko Nozaki
Journal:  Chem Sci       Date:  2015-11-03       Impact factor: 9.825

  4 in total

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