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Literature DB >> 19780109

Oxidative addition reactions of element-hydrogen bonds with different polarities to a gallium(I) compound.

Annekathrin Seifert¹, Dominik Scheid, Gerald Linti, Thomas Zessin.

Abstract

The gallium(I) derivative [Ga({N(dipp)CMe}(2)CH)] (1; dipp = 2,6-diisopropylphenyl) undergoes facile oxidative addition reactions with various element-hydrogen bonds including N-H, P-H, O-H, Sn-H, and H-H bonds. This was demonstrated by its reaction with triphenyltin hydride, ethanol, water, diethylamine, diphenylphosphane, and dihydrogen. All products were characterized by means of single-crystal X-ray structure determination, NMR spectroscopy, IR spectroscopy, and mass spectrometry.

Entities: Chemical

Year: 2009 PMID： 19780109 DOI： 10.1002/chem.200901403

Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236

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Cited

6 in total

1. Ga⁺-catalyzed hydrosilylation? About the surprising system Ga⁺/HSiR₃/olefin, proof of oxidation with subvalent Ga⁺ and silylium catalysis with perfluoroalkoxyaluminate anions.

Authors: Antoine Barthélemy; Kim Glootz; Harald Scherer; Annaleah Hanske; Ingo Krossing
Journal: Chem Sci Date: 2021-11-23 Impact factor: 9.825

2. Proton to hydride umpolung at a phosphonium center via electron relay: a new strategy for main-group based water reduction.

Authors: Takumi Oishi; Leonardo I Lugo-Fuentes; Yichuan Jing; J Oscar C Jimenez-Halla; Joaquín Barroso-Flores; Masaaki Nakamoto; Yohsuke Yamamoto; Nao Tsunoji; Rong Shang
Journal: Chem Sci Date: 2021-11-15 Impact factor: 9.825

Oxidative addition reactions of element-hydrogen bonds with different polarities to a gallium(I) compound.

1. Ga⁺-catalyzed hydrosilylation? About the surprising system Ga⁺/HSiR₃/olefin, proof of oxidation with subvalent Ga⁺ and silylium catalysis with perfluoroalkoxyaluminate anions.

2. Proton to hydride umpolung at a phosphonium center via electron relay: a new strategy for main-group based water reduction.

3. Propane dehydrogenation over extra-framework In(i) in chabazite zeolites.

4. Bis-Phosphaketenes LM(PCO)₂ (M=Ga, In): A New Class of Reactive Group 13 Metal-Phosphorus Compounds.

5. Solvent-Dependent Oxidative Addition and Reductive Elimination of H₂ Across a Gallium-Zinc Bond.

6. E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound.

Oxidative addition reactions of element-hydrogen bonds with different polarities to a gallium(I) compound.

1. Ga+-catalyzed hydrosilylation? About the surprising system Ga+/HSiR3/olefin, proof of oxidation with subvalent Ga+ and silylium catalysis with perfluoroalkoxyaluminate anions.

2. Proton to hydride umpolung at a phosphonium center via electron relay: a new strategy for main-group based water reduction.

3. Propane dehydrogenation over extra-framework In(i) in chabazite zeolites.

4. Bis-Phosphaketenes LM(PCO)2 (M=Ga, In): A New Class of Reactive Group 13 Metal-Phosphorus Compounds.

5. Solvent-Dependent Oxidative Addition and Reductive Elimination of H2 Across a Gallium-Zinc Bond.

6. E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound.

1. Ga⁺-catalyzed hydrosilylation? About the surprising system Ga⁺/HSiR₃/olefin, proof of oxidation with subvalent Ga⁺ and silylium catalysis with perfluoroalkoxyaluminate anions.

4. Bis-Phosphaketenes LM(PCO)₂ (M=Ga, In): A New Class of Reactive Group 13 Metal-Phosphorus Compounds.

5. Solvent-Dependent Oxidative Addition and Reductive Elimination of H₂ Across a Gallium-Zinc Bond.