Literature DB >> 19775157

Catalytic hydrogenation of carbon dioxide using Ir(III)-pincer complexes.

Ryo Tanaka1, Makoto Yamashita, Kyoko Nozaki.   

Abstract

Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium trihydride complex as a catalyst. Potassium formate was obtained with turnover numbers up to 3,500,000 and a turnover frequency of 150,000 h(-1), both of which are the highest values reported to date.

Entities:  

Year:  2009        PMID： 19775157     DOI： 10.1021/ja903574e

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  42 in total

Review 1.  Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation.

Authors:  Aaron M Appel; John E Bercaw; Andrew B Bocarsly; Holger Dobbek; Daniel L DuBois; Michel Dupuis; James G Ferry; Etsuko Fujita; Russ Hille; Paul J A Kenis; Cheryl A Kerfeld; Robert H Morris; Charles H F Peden; Archie R Portis; Stephen W Ragsdale; Thomas B Rauchfuss; Joost N H Reek; Lance C Seefeldt; Rudolf K Thauer; Grover L Waldrop
Journal:  Chem Rev       Date:  2013-06-14       Impact factor: 60.622

2.  Iridium-based hydride transfer catalysts: from hydrogen storage to fine chemicals.

Authors:  Zhiyao Lu; Valeriy Cherepakhin; Ivan Demianets; Paul J Lauridsen; Travis J Williams
Journal:  Chem Commun (Camb)       Date:  2018-07-10       Impact factor: 6.222

3.  Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes.

Authors:  Andrea Álvarez; Atul Bansode; Atsushi Urakawa; Anastasiya V Bavykina; Tim A Wezendonk; Michiel Makkee; Jorge Gascon; Freek Kapteijn
Journal:  Chem Rev       Date:  2017-06-28       Impact factor: 60.622

4.  Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures.

Authors:  Jonathan F Hull; Yuichiro Himeda; Wan-Hui Wang; Brian Hashiguchi; Roy Periana; David J Szalda; James T Muckerman; Etsuko Fujita
Journal:  Nat Chem       Date:  2012-03-18       Impact factor: 24.427

5.  Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO.

Authors:  Ekambaram Balaraman; Chidambaram Gunanathan; Jing Zhang; Linda J W Shimon; David Milstein
Journal:  Nat Chem       Date:  2011-07-22       Impact factor: 24.427

6.  Ruthenium (II) and Iridium (III) Complexes of N-Heterocyclic Carbene and Pyridinol Derived Bidentate Chelates: Synthesis, Characterization, and Reactivity.

Authors:  Deidra L Gerlach; Sopheavy Siek; Dalton B Burks; Jamie M Tesh; Courtney R Thompson; Robert M Vasquez; Nicholas J White; Matthias Zeller; Douglas B Grotjahn; Elizabeth T Papish
Journal:  Inorganica Chim Acta       Date:  2017-07-01       Impact factor: 2.545

7.  Computational studies on the hydride transfer barrier for the catalytic hydrogenation of CO2 by different Ni(II) complexes.

Authors:  Santu Biswas; Animesh Chowdhury; Prodyut Roy; Anup Pramanik; Pranab Sarkar
Journal:  J Mol Model       Date:  2018-08-07       Impact factor: 1.810

Review 8.  Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics.

Authors:  Amit Kumar; Prosenjit Daw; David Milstein
Journal:  Chem Rev       Date:  2021-11-02       Impact factor: 60.622

9.  Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex.

Authors:  Sylwia Kostera; Stefan Weber; Maurizio Peruzzini; Luis F Veiros; Karl Kirchner; Luca Gonsalvi
Journal:  Organometallics       Date:  2021-04-20       Impact factor: 3.876

10.  H/D exchange under mild conditions in arenes and unactivated alkanes with C6D6 and D2O using rigid, electron-rich iridium PCP pincer complexes.

Authors:  Joel D Smith; George Durrant; Daniel H Ess; Benjamin S Gelfand; Warren E Piers
Journal:  Chem Sci       Date:  2020-06-16       Impact factor: 9.825
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