Literature DB >> 19774248

Asymmetric meso-aziridine ring-opening reactions using a chiral zirconium catalyst.

Kazutaka Seki1, Rongmin Yu, Yumi Yamazaki, Yasuhiro Yamashita, Shū Kobayashi.   

Abstract

A chiral zirconium catalyst prepared from Zr(O(t)Bu)4 and a chiral tridentate BINOL was found to be effective for asymmetric meso-aziridine ring-opening reactions with aniline derivatives. The N-benzhydryl group on the product obtained was easily cleaved to give the corresponding amine in high yield under reductive conditions.

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Year:  2009        PMID: 19774248     DOI: 10.1039/b914271c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Hydrogen bonds determine the structures of the ternary heterocyclic complexes C₂H₄O···2HF, C₂H₅N···2HF and C₂H₄S···2HF: density functional theory and topological calculations.

Authors:  Boaz G Oliveira; Regiane C M U Araújo; Antônio B Carvalho; Mozart N Ramos
Journal:  J Mol Model       Date:  2011-02-08       Impact factor: 1.810

  1 in total

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